Alkyl borane-mediated metal-free ring-opening (co) polymerizations of oxygenated monomers

C Zhang, X Geng, X Zhang, Y Gnanou… - Progress in Polymer …, 2023 - Elsevier
Sensibility to environmental concerns and the actual demand for polymeric materials free of
any metal contaminants in most applications have directed research towards significant …

Silylium Ions: From Elusive Reactive Intermediates to Potent Catalysts

HFT Klare, L Albers, L Süsse, S Keess… - Chemical …, 2021 - ACS Publications
The history of silyl cations has all the makings of a drama but with a happy ending. Being
considered reactive intermediates impossible to isolate in the condensed phase for …

Identification of active sites for acidic oxygen reduction on carbon catalysts with and without nitrogen doping

Y Jia, L Zhang, L Zhuang, H Liu, X Yan, X Wang… - Nature Catalysis, 2019 - nature.com
Owing to the difficulty in controlling the dopant or defect types and their homogeneity in
carbon materials, it is still a controversial issue to identify the active sites of carbon-based …

Modular organoboron catalysts enable transformations with unprecedented reactivity

GW Yang, YY Zhang, GP Wu - Accounts of Chemical Research, 2021 - ACS Publications
Conspectus Electron-deficient boron-based catalysts with metal-free but metallomimetic
characteristics provide a versatile platform for chemical transformations. However, their …

Towards high-performance sustainable polymers via isomerization-driven irreversible ring-opening polymerization of five-membered thionolactones

P Yuan, Y Sun, X Xu, Y Luo, M Hong - Nature Chemistry, 2022 - nature.com
The development of sustainable polymers that possess useful material properties
competitive with existing petroleum-derived polymers is a crucial goal but remains a …

Perspective on Lewis Acid‐Base Interactions in Emerging Batteries

Q Lin, D Kundu, M Skyllas‐Kazacos, J Lu… - Advanced …, 2024 - Wiley Online Library
Lewis acid‐base interactions are common in chemical processes presented in diverse
applications, such as synthesis, catalysis, batteries, semiconductors, and solar cells. The …

New directions for frustrated Lewis pair chemistry

AR Jupp, DW Stephan - Trends in Chemistry, 2019 - cell.com
The concerted action of a Lewis acid and base can activate H 2 and other small molecules.
Such frustrated Lewis pairs (FLPs) have garnered much attention and prompted many …

[HTML][HTML] Recent advances in degradable synthetic polymers for biomedical applications‐Beyond polyesters

M Dirauf, I Muljajew, C Weber, US Schubert - Progress in Polymer Science, 2022 - Elsevier
Polyesters have been studied intensely over the last few decades and proved to be suitable
for a wide range of applications. Despite all benefits, drawbacks such as eg the acidification …

Main group metal polymerisation catalysts

E Fazekas, PA Lowy, MA Rahman… - Chemical Society …, 2022 - pubs.rsc.org
With sustainability at the forefront of current polymerisation research, the typically earth-
abundant, inexpensive and low-toxicity main group metals are attractive candidates for …

Recent trends in catalytic polymerizations

DJ Walsh, MG Hyatt, SA Miller, D Guironnet - ACS Catalysis, 2019 - ACS Publications
Polymers have become one of the largest and most important materials we use in daily life.
Their popularity has stemmed from their wide range of material properties combined with …