Ru-catalysed C–H functionalisations as a tool for selective organic synthesis

S Ruiz, P Villuendas, EP Urriolabeitia - Tetrahedron Letters, 2016 - Elsevier
Organic syntheses based on the activation of C–H bonds catalysed by transition metals (TM)
are of great interest because new pathways can be designed that were not previously …

Redox-neutral photocatalytic C− H carboxylation of arenes and styrenes with CO2

M Schmalzbauer, TD Svejstrup, F Fricke, P Brandt… - Chem, 2020 - cell.com
Carbon dioxide (CO 2) is an attractive one-carbon (C1) building block in terms of
sustainability and abundance. However, its low reactivity limits applications in organic …

Ortho CH Acylation of Aryl Iodides by Palladium/Norbornene Catalysis

Z Dong, J Wang, Z Ren, G Dong - Angewandte Chemie, 2015 - Wiley Online Library
Ortho CH Acylation of Aryl Iodides by Palladium/Norbornene Catalysis - Dong - 2015 -
Angewandte Chemie - Wiley Online Library Skip to Article Content Skip to Article Information …

Rhodium-catalyzed borylation of aryl 2-pyridyl ethers through cleavage of the carbon–oxygen bond: borylative removal of the directing group

H Kinuta, M Tobisu, N Chatani - Journal of the American Chemical …, 2015 - ACS Publications
The rhodium-catalyzed reaction of aryl 2-pyridyl ethers with a diboron reagent results in the
formation of arylboronic acid derivatives via activation of the C (aryl)–O bonds. The …

Merger of visible-light photoredox catalysis and C–H activation for the room-temperature C-2 acylation of indoles in batch and flow

UK Sharma, HPL Gemoets, F Schröder, T Noel… - ACS …, 2017 - ACS Publications
A mild and versatile protocol for the C–H acylation of indoles via dual photoredox/transition-
metal catalysis was established in batch and flow. The C–H bond functionalization occurred …

Acylation of (Hetero) Arenes through C H Activation with Aroyl Surrogates

XF Wu - Chemistry–A European Journal, 2015 - Wiley Online Library
In this Minireview, the major achievements in the acylation of arenes and heteroarenes by
C H activation with aroyl groups are summarized and discussed. As the products are …

Cobalt (II)-Catalyzed Intermolecular Aminocarbonylation of Indoles with Amines

P Wei, J Ying, XF Wu - Organic Letters, 2023 - ACS Publications
A cobalt (II)-catalyzed C2–H carbonylation of indoles with amines toward indole-2-
carboxamides has been developed. By employing Co (OAc) 2· 4H2O as an inexpensive …

Recent advances on the synthesis of acylindoles

SJ Yao, ZH Ren, ZH Guan - Tetrahedron Letters, 2016 - Elsevier
Acylindoles are valuable chemicals widely found in natural products, pharmaceuticals, and
biologically active compounds. They are also important synthetic building blocks for …

Ru‐Catalysed C H Arylation of Indoles and Pyrroles with Boronic Acids: Scope and Mechanistic Studies

C Sollert, K Devaraj, A Orthaber… - … A European Journal, 2015 - Wiley Online Library
Abstract The Ru‐catalysed C2 H arylation of indoles and pyrroles by using boronic acids
under oxidative conditions is reported. This reaction can be applied to tryptophan derivatives …

Synthesis of bis-heteroaryls using Grignard reagents and pyridylsulfonium salts

AM Horan, VK Duong, EM McGarrigle - Organic Letters, 2021 - ACS Publications
Herein are reported ligand-coupling reactions of Grignard reagents with pyridylsulfonium
salts. The method has wide functional group tolerance and enables the formation of bis …