An Experimental and Theoretical Insight into I2/Br2 Oxidation of Bis(pyridin‐2‐yl)Diselane and Ditellane

MC Aragoni, E Podda, S Chaudhary… - Chemistry–An Asian …, 2023 - Wiley Online Library
The reactivity between bis (pyridin‐2‐yl) diselane oPy2Se2 and ditellane oPy2Te2 (L1 and
L2, respectively; oPy= pyridyn‐2‐yl) and I2/Br2 is discussed. Single‐crystal structure …

The Nature of the Chemical Bond in Linear Three‐Body Systems: From to Mixed Chalcogen/Halogen and Trichalcogen Moieties

MC Aragoni, M Arca, FA Devillanova… - Bioinorganic …, 2007 - Wiley Online Library
The 3 centre‐4 electrons (3c‐4e) and the donor/acceptor or charge‐transfer models for the
description of the chemical bond in linear three‐body systems, such as I 3− and related …

Organotellurium halides: New ligands for transition metal complexes

Y Torubaev, A Pasynskii, P Mathur - Coordination Chemistry Reviews, 2012 - Elsevier
This review summarizes recent advances in the coordination chemistry of organotellurium
halides with an emphasis on the special features of the coordination patterns of the …

Organotellurium (II) and‐(IV) Compounds with Picolinoylbis (thioureas): From Simple 1: 1 Adducts to Multimetallic Aggregates

SS dos Santos, VD Schwade, ES Lang… - European Journal of …, 2024 - Wiley Online Library
Abstract Reactions of 2, 6‐dipicolinoylbis (N, N‐diethylthiourea)(H2LEt) with common
tellurium (IV) starting materials such as PhTeBr3 or TeBr4 yield various tellurium (IV) and …

The structural diversity of Te–I interactions within tetraorganoditelluroxane diiodides and related compounds

J Beckmann, J Bolsinger, J Spandl - Journal of Organometallic Chemistry, 2008 - Elsevier
Two tetraorganoditelluroxane diiodides (R2Te) 2OI2 (3, R= p-MeOC6H4; 5, R= Me) were
prepared by the reaction of (p-MeOC6H4) 2TeI2 (1) and (p-MeOC6H4) 2TeO (2) and the …

A novel organotellurium halide with tellurium presenting mixed oxidation states: Synthesis and structural characterization

GA Casagrande, C Raminelli, ES Lang… - Inorganica Chimica …, 2011 - Elsevier
In this work we have investigated the reaction for the obtention of an uncommon complex
salt of the organotellurium bromide class. The reaction was carried out without the isolation …

One‐Pot Synthesis and Structure of Organochalcogen Halides with Mixed Valence States

E Schulz Lang, GA Casagrande, G Manzoni de Oliveira… - 2006 - Wiley Online Library
Abstract Treatment of the diorganodichalcogenides PhEEPh (E= Se, Te) with one equivalent
of elemental halogen (bromine or iodine) in methanol followed by addition of a sulfur donor …

Supramolecular Assembling of Complex Tellurium Salts: Synthesis and Crystal Structures of {Cs[PhTeCl4]·CH3OH} and Cs[PhTeBr4]

E Schulz Lang, GM de Oliveira… - Zeitschrift für …, 2004 - Wiley Online Library
The direct reaction between PhTeCl3 and CsCl in methanol affords {Cs [PhTeCl4]· CH3OH}.
Cs [PhTeBr4] was prepared by refluxing [2‐Br‐C5NH5][PhTeBr4] and CsCl in ethanol in the …

Innovative synthetical and structural features of new aryltellurenyl iodides

E Faoro, GM de Oliveira, ES Lang… - Journal of Organometallic …, 2011 - Elsevier
The syntheses and the structural characterization of the compounds [(mes) 2 Te–Te (I)
mes],(PyH)[mesTeI 3 (I 3)](mes= mesityl= 2, 4, 6-trimethylphenyl; Py= pyridine),(PyH) 3 …

Phenyltellurium halide complexes of iron cyclopentadienyl dicarbonyl: Synthesis and molecular structures of CpFe (CO) 2 TePh, CpFe (CO) 2 TeBr 2 Ph, CpFe (CO) 2 …

YV Torubaev, AA Pasynskii, IV Skabitskii - Russian Journal of …, 2009 - Springer
The bromination of CpFe (CO) 2 TePh (I) affords the monomeric complex CpFe (CO) 2
TePhBr 2 (II) as the major product and crystals (III), being a cocrystallizate of complexes II …