Persistent and stable organic radicals: Design, synthesis, and applications

ZX Chen, Y Li, F Huang - Chem, 2021 - cell.com
Open-shell radicals are usually thermodynamically and kinetically unstable due to their
incompletely satisfied valency. However, the rapid development of radical chemistry in the …

Organic optoelectronic materials: mechanisms and applications

O Ostroverkhova - Chemical reviews, 2016 - ACS Publications
Organic (opto) electronic materials have received considerable attention due to their
applications in thin-film-transistors, light-emitting diodes, solar cells, sensors, photorefractive …

Boron-containing organic diradicaloids: dynamically modulating singlet diradical character by lewis acid–base coordination

J Guo, Y Yang, C Dou, Y Wang - Journal of the American …, 2021 - ACS Publications
Organic diradicaloids have unique open-shell structures and properties and promising
applications in organic electronics and spintronics. Incorporation of heteroatoms is an …

Coordination chemistry in the design of heterogeneous photocatalysts

C Gao, J Wang, H Xu, Y Xiong - Chemical Society Reviews, 2017 - pubs.rsc.org
Heterogeneous catalysts have been widely used for photocatalysis, which is a highly
important process for energy conversion, owing to their merits such as easy separation of …

Diradicals

M Abe - Chemical Reviews, 2013 - ACS Publications
Open-shell molecules such as radicals, carbenes, and electronically excited-state molecules
exhibit high energies, and thus, in general, they are quite reactive. 1 The short-lived species …

Pro-aromatic and anti-aromatic π-conjugated molecules: an irresistible wish to be diradicals

Z Zeng, X Shi, C Chi, JTL Navarrete… - Chemical Society …, 2015 - pubs.rsc.org
Aromaticity is an important concept to understand the stability and physical properties of π-
conjugated molecules. Recent studies on pro-aromatic and anti-aromatic molecules …

Low band gap polycyclic hydrocarbons: from closed-shell near infrared dyes and semiconductors to open-shell radicals

Z Sun, Q Ye, C Chi, J Wu - Chemical Society Reviews, 2012 - pubs.rsc.org
Low band gap (Eg< 1.5 eV) polycyclic hydrocarbons have become one of the most important
types of materials for many applications, for example, as semiconductors in organic field …

Zethrenes, Extended p-Quinodimethanes, and Periacenes with a Singlet Biradical Ground State

Z Sun, Z Zeng, J Wu - Accounts of chemical research, 2014 - ACS Publications
Conspectus Researchers have studied polycyclic aromatic hydrocarbons (PAHs) for more
than 100 years, and most PAHs in the neutral state reported so far have a closed-shell …

Explorations of the indenofluorenes and expanded quinoidal analogues

CK Frederickson, BD Rose… - Accounts of Chemical …, 2017 - ACS Publications
Conspectus Highly conjugated hydrocarbons have attracted interest for use as active
materials in electronic devices such as organic field effect transistors (OFET) and organic …

Construction of heptagon‐containing molecular nanocarbons

Chaolumen, IA Stepek, KE Yamada… - Angewandte Chemie …, 2021 - Wiley Online Library
Molecular nanocarbons containing heptagonal rings have attracted increasing interest due
to their dynamic behavior, electronic properties, aromaticity, and solid‐state packing …