Divergent gold catalysis: unlocking molecular diversity through catalyst control

CC Chintawar, AK Yadav, A Kumar… - Chemical …, 2021 - ACS Publications
The catalyst-directed divergent synthesis, commonly termed as “divergent catalysis”, has
emerged as a promising technique as it allows chartering of structurally distinct products …

The interplay of carbophilic activation and Au (I)/Au (III) catalysis: an emerging technique for 1, 2-difunctionalization of C–C multiple bonds

VW Bhoyare, AG Tathe, A Das, CC Chintawar… - Chemical Society …, 2021 - pubs.rsc.org
Gold complexes have emerged as the catalysts of choice for various functionalization
reactions of C–C multiple bonds due to their inherent carbophilic nature. In a parallel space …

Late transition metal-catalyzed hydroamination and hydroamidation

L Huang, M Arndt, K Gooßen, H Heydt… - Chemical …, 2015 - ACS Publications
This Review examines recent developments in late transition metal-catalyzed
hydroamination and-amidation reactions. A hydroamination is a reaction in which an N− H …

Silver-catalysed reactions of alkynes: recent advances

G Fang, X Bi - Chemical Society Reviews, 2015 - pubs.rsc.org
Silver is a less expensive noble metal. Superior alkynophilicity due to π-coordination with
the carbon–carbon triple bond makes silver salts ideal catalysts for alkyne-based organic …

Iron‐catalysed hydrofunctionalisation of alkenes and alkynes

MD Greenhalgh, AS Jones, SP Thomas - ChemCatChem, 2015 - Wiley Online Library
The metal‐catalysed hydrofunctionalisation of alkenes and alkynes provides a convenient
and atom‐economic route to diversely functionalised products with control of regio‐, chemo …

Tris (pentafluorophenyl) borane and beyond: modern advances in borylation chemistry

JR Lawson, RL Melen - Inorganic chemistry, 2017 - ACS Publications
As main-group chemistry, in particular boron chemistry, has expanded and developed over
the past 20 years, one reagent has risen to prominence as well. Tris (pentafluorophenyl) …

Copper-Catalyzed Amino Lactonization and Amino Oxygenation of Alkenes Using O-Benzoylhydroxylamines

BN Hemric, K Shen, Q Wang - Journal of the American Chemical …, 2016 - ACS Publications
A copper-catalyzed amino lactonization of unsaturated carboxylic acids has been achieved
as well as the analogous intermolecular three-component amino oxygenation of olefins. The …

Silver and platinum-catalysed addition of O–H and N–H bonds to allenes

MP Muñoz - Chemical Society Reviews, 2014 - pubs.rsc.org
Transition-metal catalysed nucleophile addition to allenes is a very powerful tool for the
synthesis of functionalised molecules containing heteroatoms, heterocycles in the …

Deep eutectic mixtures: Promising sustainable solvents for metal‐catalysed and metal‐mediated organic reactions

J García‐Álvarez - European Journal of Inorganic Chemistry, 2015 - Wiley Online Library
This microreview is intended to cover the progress made in metal‐mediated and metal‐
catalysed organic reactions performed in a new family of inexpensive, greener and …

[HTML][HTML] Recent developments in alkene hydro-functionalisation promoted by homogeneous catalysts based on earth abundant elements: formation of C–N, C–O and …

V Rodriguez-Ruiz, R Carlino… - Dalton …, 2015 - pubs.rsc.org
This Perspective article provides an overview of the recent advancements in the field of intra-
and inter-molecular C–N, C–O and C–P bond formation by hydroamination …