Gas chromatography coupled to atmospheric pressure ionization mass spectrometry (GC-API-MS)

DX Li, L Gan, A Bronja, OJ Schmitz - Analytica chimica acta, 2015 - Elsevier
Although the coupling of GC/MS with atmospheric pressure ionization (API) has been
reported in 1970s, the interest in coupling GC with atmospheric pressure ion source was …

Generation of ion-bound solvent clusters as reactant ions in dopant-assisted APPI and APLI

S Klee, S Albrecht, V Derpmann, H Kersten… - Analytical and …, 2013 - Springer
We provide experimental and theoretical evidence that the primary ionization process in the
dopant-assisted varieties of the atmospheric pressure ionization methods atmospheric …

Gas flow dynamics in inlet capillaries: evidence for non laminar conditions

W Wißdorf, D Müller, Y Brachthäuser… - Journal of The …, 2016 - ACS Publications
In this work, the characteristics of gas flow in inlet capillaries are examined. Such inlet
capillaries are widely used as a first flow restriction stage in commercial atmospheric …

A novel APPI-MS setup for in situ degradation product studies of atmospherically relevant compounds: capillary atmospheric pressure photo ionization (cAPPI)

H Kersten, V Derpmann, I Barnes… - Journal of the American …, 2011 - Springer
We report on the development of a novel atmospheric pressure photoionization setup and its
applicability for in situ degradation product studies of atmospherically relevant compounds …

The role of ion‐bound cluster formation in negative ion mass spectrometry

V Derpmann, S Albrecht… - Rapid Communications in …, 2012 - Wiley Online Library
RATIONALE The ionization mechanisms operative in negative ion atmospheric pressure
mass spectrometry are far from being properly understood. In an excess of oxygen …

Capillary atmospheric pressure electron capture ionization (cAPECI): a highly efficient ionization method for nitroaromatic compounds

V Derpmann, D Mueller, I Bejan… - Journal of the …, 2014 - ACS Publications
We report on a novel method for atmospheric pressure ionization of compounds with
elevated electron affinity (eg, nitroaromatic compounds) or gas phase acidity (eg, phenols) …

Evaluation of the performance of small diode pumped UV solid state (DPSS) Nd: YAG lasers as new radiation sources for atmospheric pressure laser ionization mass …

H Kersten, M Lorenz, KJ Brockmann… - Journal of The American …, 2011 - ACS Publications
The performance of a KrF* bench top excimer laser and a compact diode pumped UV solid
state (DPSS) Nd: YAG laser as photo-ionizing source in LC-APLI MS is compared. The …

[图书][B] Development of a highly sensitive and versatile mass spectrometer system for laboratory and atmospheric measurements

S Albrecht - 2014 - juser.fz-juelich.de
Trace gases in the upper troposphere and the lower stratosphere (UTLS) strongly influence
our climate and even can affect tropospheric weather. Therefore a better understanding of …

Studies of the mechanism of the cluster formation in a thermally sampling atmospheric pressure ionization mass spectrometer

S Albrecht, S Klopotowski, V Derpmann… - Review of Scientific …, 2014 - pubs.aip.org
In this study a thermally sampling atmospheric pressure ionization mass spectrometer is
described and characterized. The ion transfer stage offers the capability to sample cluster …

[PDF][PDF] Charakterisierung und Optimierung von Corona-Mikroplasma initiierten Ionisationsprozessen zur Anwendung in der Atmosphärendruckionisations …

S Klee - 2014 - elekpub.bib.uni-wuppertal.de
Ionization methods operating at atmospheric pressure have largely affected the
development of analytical mass spectrometry. Today, virtually every atmospheric pressure …