Quantum chemical studies of light harvesting

C Curutchet, B Mennucci - Chemical reviews, 2017 - ACS Publications
The design of optimal light-harvesting (supra) molecular systems and materials is one of the
most challenging frontiers of science. Theoretical methods and computational models play a …

Supramolecular approach towards light-harvesting materials based on porphyrins and chlorophylls

J Otsuki - Journal of Materials Chemistry A, 2018 - pubs.rsc.org
Photosynthesis is one of the most important processes that supplies the energy required for
the survival of all living things. The initial process is the absorption of sunlight by a …

Ultrafast charge transfer coupled with lattice phonons in two-dimensional covalent organic frameworks

TW Kim, S Jun, Y Ha, RK Yadav, A Kumar… - Nature …, 2019 - nature.com
Covalent organic frameworks (COFs) have emerged as a promising light-harvesting module
for artificial photosynthesis and photovoltaics. For efficient generation of free charge carriers …

From fundamental theories to quantum coherences in electron transfer

SR Rather, GD Scholes - Journal of the American Chemical …, 2018 - ACS Publications
Photoinduced electron transfer (ET) is a cornerstone of energy transduction from light to
chemistry. The past decade has seen tremendous advances in the possible role of quantum …

Ultrafast anisotropy decay reveals structure and energy transfer in supramolecular aggregates

V Erić, JL Castro, X Li, L Dsouza… - The Journal of …, 2023 - ACS Publications
Chlorosomes from green bacteria perform the most efficient light capture and energy
transfer, as observed among natural light-harvesting antennae. Hence, their unique …

Manifestation of hydrogen bonding and exciton delocalization on the absorption and two-dimensional electronic spectra of chlorosomes

V Eric, X Li, L Dsouza, SK Frehan… - The Journal of …, 2023 - ACS Publications
Chlorosomes are supramolecular aggregates that contain thousands of bacteriochlorophyll
molecules. They perform the most efficient ultrafast excitation energy transfer of all natural …

Potential pitfalls of the early-time dynamics in two-dimensional electronic spectroscopy

D Paleček, P Edlund, E Gustavsson… - The Journal of …, 2019 - pubs.aip.org
Two-dimensional electronic spectroscopy, and especially the polarization-controlled version
of it, is the cutting edge technique for disentangling various types of coherences in …

Quantum mechanics of excitation transport in photosynthetic complexes: a key issues review

F Levi, S Mostarda, F Rao… - Reports on Progress in …, 2015 - iopscience.iop.org
For a long time microscopic physical descriptions of biological processes have been based
on quantum mechanical concepts and tools, and routinely employed by chemical physicists …

Dynamic disorder drives exciton transfer in tubular chlorosomal assemblies

X Li, F Buda, HJM de Groot… - The Journal of Physical …, 2020 - ACS Publications
Chlorosomes stand out for their highly efficient excitation energy transfer (EET) in extreme
low light conditions. Yet, little is known about the EET when a chlorosome is excited to a …

Probing ultrafast excitation energy transfer of the chlorosome with exciton–phonon variational dynamics

AS Márquez, L Chen, K Sun, Y Zhao - Physical Chemistry Chemical …, 2016 - pubs.rsc.org
The chlorosome antenna complex is a fascinating structure which due to its immense scale,
accurate simulation of excitation energy transfer (EET) dynamics supposes a genuine …