The study of gas phase ion–molecule reactions by state-of-the-art mass spectrometric
experiments in conjunction with quantum chemistry calculations offers an opportunity to …

Recent studies on reactions between Mo x O y− cluster anions and H 2 O/C 2 H 4 mixtures
revealed a complex web of addition, hydrogen evolution, and chemifragmentation reactions …

Mixed-metal oxides have proven to be effective catalysts for the hydrogen evolution reaction,
often outperforming either of the binary metal oxides. The reactivity of Mn x MoO y−(x= 1, 2; …

The freeze–dry pulsated orifice ejection method (FD-POEM) can be coupled with plasma
spheroidization (PS) as an advanced approach for fabricating spherical refractory powders …

A study of reactions between a distribution of 98 Mo x S y-clusters ranging from sub-sulfide
(x∼ y) to hypersulfide (y> 2x) is presented, compared with previous studies on homologous …

Lanthanide (Ln) oxide clusters have complex electronic structures arising from the partially
occupied Ln 4f subshell. New anion photoelectron (PE) spectra of Sm x Ce 3− x O y−(x= 0 …

Metal oxide cluster models of catalyst materials offer a powerful platform for probing the
molecular-scale features and interactions that govern catalysis. This perspective gives an …

To probe the mechanism of sacrificial reagents in catalytic processes, product distributions
from Mo x O y–clusters reacting individually with C2H4 and H2O are compared with those …

The interactions of vanadium monoxide anion (VO−) with water were investigated by density
functional calculation. The theoretical calculations confirmed that HOV (OH)− was generated …

Methods based on quantum mechanics can accurately describe chemical systems but at a
high computational cost. The steep computational scaling of popular quantum chemical …