The advent of sulfur (vi)-fluoride exchange (SuFEx) processes as transformations with click-
like reactivity has invigorated research into electrophilic species featuring a sulfur–fluorine …

Organosulfur compounds have long played a vital role in organic chemistry and in the
development of novel chemical structures and architectures. Prominent among these …

Conventionally, sulfones are prepared by oxidation of sulfides with strong oxidants. Now, a
multicomponent reductive cross‐coupling involving an inorganic salt (sodium metabisulfite) …

Simple access to aryl sulfinates from aryl iodides and bromides is reported using an
inexpensive Ni‐electrocatalytic protocol. The reaction exhibits a broad scope, uses stock …

This review is focused on the recent advances in the chemistry of sulfur dioxide fixation
through a radical process. Diverse sulfonyl compounds can be obtained efficiently under …

The reactivity of the sulfonyl group varies dramatically from nucleophilic sulfinates through
chemically robust sulfones to electrophilic sulfonyl halides—a feature that has been used …

A catalyst‐free approach for the generation of sulfonyl radicals from aryldiazonium
tetrafluoroborates in the presence of DABCO⋅(SO2) 2 is realized. The combination of …

Recent advances in the sulfonylation reactions by using inorganic sulfites as the source of
sulfonyl group are reported. The approaches employing inorganic sulfites as sulfur dioxide …

Molecules containing a sulfonyl functionality, such as sulfones, sulfonyl chlorides or
sulfonamides play an important role in organic chemistry and have found widespread …

For a while, the reactivity of gold complexes was largely dominated by their Lewis acid
behavior. In contrast to the other transition metals, the elementary steps of organometallic …