Radical ligand-containing single-molecule magnets
Single-molecule magnets represent the ultimate size limit for spin-based information storage
and processing; however, such applications require large spin relaxation barriers and …
and processing; however, such applications require large spin relaxation barriers and …
Main group chemistry at the interface with molecular magnetism
Innovative synthetic coordination and, increasingly, organometallic chemistry are at the
heart of advances in molecular magnetism. Smart ligand design is essential for …
heart of advances in molecular magnetism. Smart ligand design is essential for …
Manipulating on/off single-molecule magnet behavior in a Dy (III)-based photochromic complex
YJ Ma, JX Hu, SD Han, J Pan, JH Li… - Journal of the American …, 2020 - ACS Publications
Exploitation of room temperature (RT) photochromism and photomagnetism to induce single-
molecule magnet (SMM) behavior has potential applications toward optical switches and …
molecule magnet (SMM) behavior has potential applications toward optical switches and …
Taming Super-Reduced Bi23– Radicals with Rare Earth Cations
Here, we report the synthesis of two new sets of dibismuth-bridged rare earth molecules.
The first series contains a bridging diamagnetic Bi22–anion,(Cp* 2RE) 2 (μ-η2: η2-Bi2), 1 …
The first series contains a bridging diamagnetic Bi22–anion,(Cp* 2RE) 2 (μ-η2: η2-Bi2), 1 …
[HTML][HTML] Giant coercivity and high magnetic blocking temperatures for N23− radical-bridged dilanthanide complexes upon ligand dissociation
Increasing the operating temperatures of single-molecule magnets—molecules that can
retain magnetic polarization in the absence of an applied field—has potential implications …
retain magnetic polarization in the absence of an applied field—has potential implications …
Substituent effects on exchange coupling and magnetic relaxation in 2, 2′-bipyrimidine radical-bridged dilanthanide complexes
Systematic analysis of related compounds is crucial to the design of single-molecule
magnets with improved properties, yet such studies on multinuclear lanthanide complexes …
magnets with improved properties, yet such studies on multinuclear lanthanide complexes …
Lanthanide single molecule magnets: progress and perspective
P Zhang, L Zhang, J Tang - Dalton Transactions, 2015 - pubs.rsc.org
The last few years have seen a huge renaissance in the study of single molecule magnets
(SMMs) thanks to the extensive applications of lanthanide ions with large inherent …
(SMMs) thanks to the extensive applications of lanthanide ions with large inherent …
Recent Developments in Lanthanide Single‐Molecule Magnets
J Lu, M Guo, J Tang - Chemistry–An Asian Journal, 2017 - Wiley Online Library
Single‐molecule magnets (SMMs) exhibiting slow relaxation of magnetization of purely
molecular origin are highly attractive owing to their potential applications in spintronic …
molecular origin are highly attractive owing to their potential applications in spintronic …
Lanthanide–radical single-molecule magnets: current status and future challenges
HD Li, SG Wu, ML Tong - Chemical Communications, 2023 - pubs.rsc.org
In the field of molecular magnetism, the lanthanide–radical (Ln–Rad) method has become
one of the most appealing tactics for introducing strong magnetic interactions and has …
one of the most appealing tactics for introducing strong magnetic interactions and has …
Radical‐Bridged Ln4 Metallocene Complexes with Strong Magnetic Coupling and a Large Coercive Field
Inducing magnetic coupling between 4f elements is an ongoing challenge. To overcome this
formidable difficulty, we incorporate highly delocalized tetrazinyl radicals, which strongly …
formidable difficulty, we incorporate highly delocalized tetrazinyl radicals, which strongly …