Radical ligand-containing single-molecule magnets

S Demir, IR Jeon, JR Long, TD Harris - Coordination Chemistry Reviews, 2015 - Elsevier
Single-molecule magnets represent the ultimate size limit for spin-based information storage
and processing; however, such applications require large spin relaxation barriers and …

Main group chemistry at the interface with molecular magnetism

FS Guo, AK Bar, RA Layfield - Chemical reviews, 2019 - ACS Publications
Innovative synthetic coordination and, increasingly, organometallic chemistry are at the
heart of advances in molecular magnetism. Smart ligand design is essential for …

Manipulating on/off single-molecule magnet behavior in a Dy (III)-based photochromic complex

YJ Ma, JX Hu, SD Han, J Pan, JH Li… - Journal of the American …, 2020 - ACS Publications
Exploitation of room temperature (RT) photochromism and photomagnetism to induce single-
molecule magnet (SMM) behavior has potential applications toward optical switches and …

Taming Super-Reduced Bi23– Radicals with Rare Earth Cations

P Zhang, R Nabi, JK Staab, NF Chilton… - Journal of the American …, 2023 - ACS Publications
Here, we report the synthesis of two new sets of dibismuth-bridged rare earth molecules.
The first series contains a bridging diamagnetic Bi22–anion,(Cp* 2RE) 2 (μ-η2: η2-Bi2), 1 …

[HTML][HTML] Giant coercivity and high magnetic blocking temperatures for N23− radical-bridged dilanthanide complexes upon ligand dissociation

S Demir, MI Gonzalez, LE Darago, WJ Evans… - Nature …, 2017 - nature.com
Increasing the operating temperatures of single-molecule magnets—molecules that can
retain magnetic polarization in the absence of an applied field—has potential implications …

Substituent effects on exchange coupling and magnetic relaxation in 2, 2′-bipyrimidine radical-bridged dilanthanide complexes

CA Gould, E Mu, V Vieru, LE Darago… - Journal of the …, 2020 - ACS Publications
Systematic analysis of related compounds is crucial to the design of single-molecule
magnets with improved properties, yet such studies on multinuclear lanthanide complexes …

Lanthanide single molecule magnets: progress and perspective

P Zhang, L Zhang, J Tang - Dalton Transactions, 2015 - pubs.rsc.org
The last few years have seen a huge renaissance in the study of single molecule magnets
(SMMs) thanks to the extensive applications of lanthanide ions with large inherent …

Recent Developments in Lanthanide Single‐Molecule Magnets

J Lu, M Guo, J Tang - Chemistry–An Asian Journal, 2017 - Wiley Online Library
Single‐molecule magnets (SMMs) exhibiting slow relaxation of magnetization of purely
molecular origin are highly attractive owing to their potential applications in spintronic …

Lanthanide–radical single-molecule magnets: current status and future challenges

HD Li, SG Wu, ML Tong - Chemical Communications, 2023 - pubs.rsc.org
In the field of molecular magnetism, the lanthanide–radical (Ln–Rad) method has become
one of the most appealing tactics for introducing strong magnetic interactions and has …

Radical‐Bridged Ln4 Metallocene Complexes with Strong Magnetic Coupling and a Large Coercive Field

N Mavragani, D Errulat, DA Gálico, AA Kitos… - Angewandte …, 2021 - Wiley Online Library
Inducing magnetic coupling between 4f elements is an ongoing challenge. To overcome this
formidable difficulty, we incorporate highly delocalized tetrazinyl radicals, which strongly …