Abstract The phenomenon of “Conservatively Perturbed Equilibrium”(CPE) in chemical
kinetics is distinguished using a sequence of first-order reactions (linear mechanism) and …

Joint kinetics, a new paradigm for chemical kinetics and chemical engineering, is proposed.
Its main idea is performing a battery of kinetic experiments from special initial compositions …

The exact autonomous (time-independent) kinetic invariants of nonlinear chemical reactions
occurring in open systems with the participation of an independent and any number of …

The “conservatively perturbed equilibrium”(CPE) technique for a complex chemical system
is computationally analyzed in a batch reactor considering different linear mechanisms with …

Kinetic events (intersections, maxima and coincidences) are mapped in the batch reactor
(BR) and the continuously stirred-tank reactor (CSTR). The mechanism A→ B⇄ C was used …

This study aims at determining both the rate constants of chlorination of p-xylene with
molecular chlorine and FeCl 3 as a catalyst at 70° C and 90° C and the related chemical …

A method has been developed for calculating the exact autonomous kinetic invariants of
multistage linear chemical reactions occurring in a gradientless isothermal reactor via any …

Mathematical models of nonequilibrium processes in distributed systems are described by
partial differential equations with given boundary conditions and, as a rule, cannot be solved …

Fast changes in the kinetic characteristics occur at the beginning of the transition processes
of nonlinear chemical reactions, which are often not observed during nonstationary …

Обсуждаются ограничения дуал-метода и его расширенной версии-метода мульти-
экспериментов при определении точных временных кинетических …