High power and energy density aqueous proton battery operated at− 90° C

T Sun, H Du, S Zheng, J Shi… - Advanced Functional …, 2021 - Wiley Online Library
Freezing electrolyte and sluggish ionic migration kinetics limited the low‐temperature
performance of rechargeable batteries. Here, an aqueous proton battery is developed …

Carbones and carbon atom as ligands in transition metal complexes

L Zhao, C Chai, W Petz, G Frenking - Molecules, 2020 - mdpi.com
This review summarizes experimental and theoretical studies of transition metal complexes
with two types of novel metal-carbon bonds. One type features complexes with carbones …

Air-stable thermoluminescent carbodicarbene-borafluorenium ions

KK Hollister, A Molino, G Breiner… - Journal of the …, 2022 - ACS Publications
Borenium ions, originally synthesized as fundamentally important laboratory curiosities,
have attracted significant attention due to their applications in catalysis and frustrated Lewis …

Geminal dianions stabilized by main group elements

M Fustier-Boutignon, N Nebra, N Mézailles - Chemical reviews, 2019 - ACS Publications
This review is dedicated to the chemistry of stable and isolable species that bear two lone
pairs at the same C center, ie, geminal dianions, stabilized by main group elements. Three …

The emergence of zerovalent carbon compounds from structural curiosities to organocatalysts

AL Liberman-Martin - Cell Reports Physical Science, 2023 - cell.com
Low-valent main group compounds have reactivity patterns and properties reminiscent of
transition metals. While divalent carbon compounds such as carbenes are widely studied …

Pentacyclic Fused Diborepinium Ions with Carbene-and Carbone-Mediated Deep-Blue to Red Emission

K Hollister, A Molino, VVV Le, N Jones, W Smith… - Chemical …, 2024 - pubs.rsc.org
Designing molecules that can undergo late-stage modifications resulting in specific optical
properties is useful for developing structure-function trends in materials, which ultimately …

Isolation of a Uranium (III)‐Carbon Multiple Bond Complex

W Su, Y Ma, L Xiang, J Wang, S Wang… - … A European Journal, 2021 - Wiley Online Library
Low‐valent uranium‐element multiple bond complexes remain scarce, though there is
burgeoning interest regarding to their bonding and reactivity. Herein, isolation of a uranium …

An Experimental and Theoretical Study of the Structures and Properties of [CDPMe‐Ni(CO)3] and [Ni2(CO)42‐CO)(µ2‐CDPMe)]

K Flosdorf, D Jiang, L Zhao, B Neumüller… - European Journal of …, 2019 - Wiley Online Library
The reaction of sym‐dimethyltetraphenyl carbodiphosphorane (CDPMe) with [Ni (CO) 4]
under standard conditions yields the CDPMe‐and carbon monoxide‐bridged dinickel …

Diffusion NMR spectroscopy applied to coordination and organometallic compounds

Á Raya-Barón, P Oña-Burgos, I Fernández - Annual Reports on NMR …, 2019 - Elsevier
This chapter illustrates an extensive review of the application of diffusion NMR techniques
on coordination compounds and organometallic systems that gives an idea of the …

Flexible coordination of carbodiphosphorane-based pincer ligands in chromium (0) carbonyl complexes

L Maser, P Korziniowski… - Canadian Journal of …, 2021 - cdnsciencepub.com
A series of chromium (0) complexes was obtained by subsequent irradiation of [Cr (CO) 6] in
the presence of [(Ph2P-CH2-PPh2) 2CH]+. Depending on the reaction conditions and the …