Functionalization of fluorinated molecules by transition-metal-mediated C–F bond activation to access fluorinated building blocks

T Ahrens, J Kohlmann, M Ahrens, T Braun - Chemical Reviews, 2015 - ACS Publications
Fluorinated organic compounds increasingly gain importance in numerous areas of
chemistry and everyday life. Building blocks which contain fluorinated entities are of high …

Nickel-catalyzed cross-couplings involving carbon− oxygen bonds

BM Rosen, KW Quasdorf, DA Wilson, N Zhang… - Chemical …, 2011 - ACS Publications
REVIEW intricate molecular topologies and architectures. To turn the molecular dreams into
a reality, synthetic chemists must ultimately roll up their sleeves and become molecular …

Synthesis of fluorinated compounds by Nickel-catalyzed defluorinative cross-coupling reactions

K Wang, W Kong - ACS Catalysis, 2023 - ACS Publications
Organofluorine compounds have attracted extensive attention in various industrial fields due
to their unique chemical and physical properties. Despite increasing demand in a wide …

Synthesis of fluorinated building blocks by transition‐metal‐mediated hydrodefluorination reactions

MF Kuehnel, D Lentz, T Braun - … Chemie International Edition, 2013 - Wiley Online Library
The activation and functionalization of carbon–fluorine bonds can be considered as a major
challenge in organometallic chemistry. The growing demand for means to introduce fluorine …

Selective photocatalytic C–F borylation of polyfluoroarenes by Rh/Ni dual catalysis providing valuable fluorinated arylboronate esters

YM Tian, XN Guo, MW Kuntze-Fechner… - Journal of the …, 2018 - ACS Publications
A highly selective and general photocatalytic C–F borylation protocol that employs a
rhodium biphenyl complex as a triplet sensitizer and the nickel catalyst [Ni (IMes) 2](IMes= 1 …

Ni/Cu-catalyzed defluoroborylation of fluoroarenes for diverse C–F bond functionalizations

T Niwa, H Ochiai, Y Watanabe… - Journal of the American …, 2015 - ACS Publications
Ni/Cu-catalyzed transformation of fluoroarenes to arylboronic acid pinacol esters via C–F
bond cleavage has been achieved. Further versatile derivatization of an arylboronic ester …

Halogen bonding in metal–organic–supramolecular networks

R Bertani, P Sgarbossa, A Venzo, F Lelj… - Coordination Chemistry …, 2010 - Elsevier
Halogen bonding (XB) has been recently exploited as a significant tool for engineering
crystals involving coordination and organometallic compounds as tectons. This review, in …

Catalytic C− C bond formation accomplished by selective C− F activation of perfluorinated arenes

T Schaub, M Backes, U Radius - Journal of the American …, 2006 - ACS Publications
Catalytic C−C Bond Formation Accomplished by Selective C−F Activation of Perfluorinated
Arenes | Journal of the American Chemical Society ACS ACS Publications C&EN CAS Find …

Stereoselective Palladium-Catalyzed Base-Free Suzuki–Miyaura Cross-Coupling of Tetrasubstituted gem-Difluoroalkenes: An Experimental and Computational …

Y Wang, X Qi, Q Ma, P Liu, GC Tsui - ACS Catalysis, 2021 - ACS Publications
Palladium-catalyzed Suzuki–Miyaura cross-coupling reactions are among the most powerful
tools for constructing carbon–carbon bonds. Moreover, the selective coupling between gem …

Cross coupling reactions of polyfluoroarenes via C–F activation

AD Sun, JA Love - Dalton Transactions, 2010 - pubs.rsc.org
Cross coupling reactions of polyfluoroarenes via C–F activation - Dalton Transactions (RSC
Publishing) DOI:10.1039/C0DT00540A Royal Society of Chemistry View PDF VersionPrevious …