Towards the quantification of 5f delocalization
By using M4, 5 X-ray Emission Spectroscopy (XES) in the tender X-ray regime, it is possible
to quantify 5f delocalization in the actinides. Previous analyses, utilizing the Branching Ratio …
to quantify 5f delocalization in the actinides. Previous analyses, utilizing the Branching Ratio …
The apparent absence of chemical sensitivity in the 4d and 5d X-ray absorption spectroscopy of uranium compounds
JG Tobin - Journal of Electron Spectroscopy and Related …, 2014 - Elsevier
Recently, X-ray absorption spectroscopy (XAS) and related derivative measurements have
been used to demonstrate that the Pu 5f states are strongly relativistic and have a 5f …
been used to demonstrate that the Pu 5f states are strongly relativistic and have a 5f …
The Limitations of 5f Delocalization and Dispersion
Delocalization in the 5f states of the actinides is an important phenomenon, but poorly
quantified. Here, the fundamental limitations of 5f dispersion measurements using angle and …
quantified. Here, the fundamental limitations of 5f dispersion measurements using angle and …
An empirical analysis of α-U Bremsstrahlung Isochromat Spectroscopy
JG Tobin - MRS Advances, 2022 - Springer
Based solely upon the previously reported (1) Bremsstrahlung Isochromat Spectroscopy
(BIS) data for αU and (2) the known values for the 5f5/2 and 5f7/2 populations of αU, it is …
(BIS) data for αU and (2) the known values for the 5f5/2 and 5f7/2 populations of αU, it is …
Splittings, satellites and fine structure in the soft X-ray spectroscopy of the actinides
JG Tobin, SW Yu, BW Chung - Topics in Catalysis, 2013 - Springer
Perhaps the most demanding and powerful actinide spectroscopy is that using soft X-ray
and VUV photons. Because of the relatively low energy and fairly small sampling depths of …
and VUV photons. Because of the relatively low energy and fairly small sampling depths of …
Electron spectroscopy of the oxidation and aging of U and Pu
JG Tobin, DK Shuh - Journal of Electron Spectroscopy and Related …, 2015 - Elsevier
Uranium and Plutonium are highly reactive elements that undergo not only chemical
reactions but also nuclear reactions. This can lead to possibly significant materials …
reactions but also nuclear reactions. This can lead to possibly significant materials …
Enhanced spin–orbit coupling in the underscreened Anderson lattice model for itinerant 5f metals
X Yuan, PS Riseborough, EJ Calegari… - Electronic …, 2021 - iopscience.iop.org
We investigate the effect of many-body interactions on the spin–orbit coupling of anisotropic
metals. We use the underscreened Anderson lattice model that was proposed to describe …
metals. We use the underscreened Anderson lattice model that was proposed to describe …
Narrowing the range of possible solutions to the Pu electronic structure problem: Developing a new Bremstrahlung Isochromat Spectroscopy capability
JG Tobin, SW Yu, BW Chung, GD Waddill… - IOP Conference …, 2010 - iopscience.iop.org
Abstract Bremstrahlung Isochromat Spectroscopy (BIS) has a proven record for the probing
of unoccupied electronic structure, including feasibility studies of actinides such as U and …
of unoccupied electronic structure, including feasibility studies of actinides such as U and …
Resolving the Pu electronic structure enigma: Past lessons and future directions
JG Tobin, SW Yu, BW Chung, GD Waddill - Journal of nuclear materials, 2009 - Elsevier
The nature and limitations of the photoelectron spectroscopy (PES) of Pu is discussed,
particularly the absence of detailed fine structure. A novel experiment, Fano Spectroscopy, is …
particularly the absence of detailed fine structure. A novel experiment, Fano Spectroscopy, is …
Enhanced Spin Orbit Interaction in Actinides
X Yuan, PS Riseborough, E Calegari… - Journal of Physics …, 2022 - iopscience.iop.org
We investigate the effect of many-body interactions on the spin-orbit coupling of anisotropic
metals. We use the Underscreened Anderson Lattice Model that was proposed to describe …
metals. We use the Underscreened Anderson Lattice Model that was proposed to describe …