Towards the quantification of 5f delocalization

JG Tobin, S Nowak, SW Yu, R Alonso-Mori, T Kroll… - Applied Sciences, 2020 - mdpi.com
By using M4, 5 X-ray Emission Spectroscopy (XES) in the tender X-ray regime, it is possible
to quantify 5f delocalization in the actinides. Previous analyses, utilizing the Branching Ratio …

The apparent absence of chemical sensitivity in the 4d and 5d X-ray absorption spectroscopy of uranium compounds

JG Tobin - Journal of Electron Spectroscopy and Related …, 2014 - Elsevier
Recently, X-ray absorption spectroscopy (XAS) and related derivative measurements have
been used to demonstrate that the Pu 5f states are strongly relativistic and have a 5f …

The Limitations of 5f Delocalization and Dispersion

JG Tobin, S Nowak, SW Yu, R Alonso-Mori, T Kroll… - Applied Sciences, 2021 - mdpi.com
Delocalization in the 5f states of the actinides is an important phenomenon, but poorly
quantified. Here, the fundamental limitations of 5f dispersion measurements using angle and …

An empirical analysis of α-U Bremsstrahlung Isochromat Spectroscopy

JG Tobin - MRS Advances, 2022 - Springer
Based solely upon the previously reported (1) Bremsstrahlung Isochromat Spectroscopy
(BIS) data for αU and (2) the known values for the 5f5/2 and 5f7/2 populations of αU, it is …

Splittings, satellites and fine structure in the soft X-ray spectroscopy of the actinides

JG Tobin, SW Yu, BW Chung - Topics in Catalysis, 2013 - Springer
Perhaps the most demanding and powerful actinide spectroscopy is that using soft X-ray
and VUV photons. Because of the relatively low energy and fairly small sampling depths of …

Electron spectroscopy of the oxidation and aging of U and Pu

JG Tobin, DK Shuh - Journal of Electron Spectroscopy and Related …, 2015 - Elsevier
Uranium and Plutonium are highly reactive elements that undergo not only chemical
reactions but also nuclear reactions. This can lead to possibly significant materials …

Enhanced spin–orbit coupling in the underscreened Anderson lattice model for itinerant 5f metals

X Yuan, PS Riseborough, EJ Calegari… - Electronic …, 2021 - iopscience.iop.org
We investigate the effect of many-body interactions on the spin–orbit coupling of anisotropic
metals. We use the underscreened Anderson lattice model that was proposed to describe …

Narrowing the range of possible solutions to the Pu electronic structure problem: Developing a new Bremstrahlung Isochromat Spectroscopy capability

JG Tobin, SW Yu, BW Chung, GD Waddill… - IOP Conference …, 2010 - iopscience.iop.org
Abstract Bremstrahlung Isochromat Spectroscopy (BIS) has a proven record for the probing
of unoccupied electronic structure, including feasibility studies of actinides such as U and …

Resolving the Pu electronic structure enigma: Past lessons and future directions

JG Tobin, SW Yu, BW Chung, GD Waddill - Journal of nuclear materials, 2009 - Elsevier
The nature and limitations of the photoelectron spectroscopy (PES) of Pu is discussed,
particularly the absence of detailed fine structure. A novel experiment, Fano Spectroscopy, is …

Enhanced Spin Orbit Interaction in Actinides

X Yuan, PS Riseborough, E Calegari… - Journal of Physics …, 2022 - iopscience.iop.org
We investigate the effect of many-body interactions on the spin-orbit coupling of anisotropic
metals. We use the Underscreened Anderson Lattice Model that was proposed to describe …