The mechanochemical synthesis of polymers

A Krusenbaum, S Grätz, GT Tigineh… - Chemical Society …, 2022 - pubs.rsc.org
Mechanochemistry–the utilization of mechanical forces to induce chemical reactions–is a
rarely considered tool for polymer synthesis. It offers numerous advantages such as reduced …

Shake, shear, and grind!–the evolution of mechanoredox polymerization methodology

SM Zeitler, MR Golder - Chemical Communications, 2024 - pubs.rsc.org
In the last half decade, mechanoredox catalysis has enabled an entirely new genre of
polymerization methodology. In this paradigm, mechanical force, such as ultrasonic …

Fragmentation versus cohesion

E Villermaux - Journal of Fluid Mechanics, 2020 - cambridge.org
Capillarity is the familiar manifestation of the cohesion of liquids. Since Laplace (Traité de
mécanique céleste, vol. IV, supplément au livre X: Sur l'action capillaire, 1805, pp. 1–65), we …

Mechanochemical Synthesis of Corannulene‐Based Curved Nanographenes

G Báti, D Csókás, T Yong, SM Tam… - Angewandte …, 2020 - Wiley Online Library
It is shown that corannulene‐based strained π‐surfaces can be obtained through the use of
mechanochemical Suzuki and Scholl reactions. Besides being solvent‐free, the …

Synthesis of precisely functionalizable curved nanographenes via graphitization-induced regioselective chlorination in a mechanochemical Scholl Reaction

J Stanojkovic, R William, Z Zhang, I Fernández… - Nature …, 2023 - nature.com
While the synthesis of nanographenes has advanced greatly in the past few years,
development of their atomically precise functionalization strategies remains rare. The ability …

Eco-Friendly Production of Hyper-Cross-Linked Polymers Using Mechanosynthesis and Bioresources: A Critical Review

AM Borrero-López, A Celzard… - … Sustainable Chemistry & …, 2022 - ACS Publications
Hyper-cross-linked polymers (HCPs) are receiving great attention due to their high specific
surface areas, allowing them to offer high performances in many different applications …

Thiophene-embedded conjugated microporous polymers for photocatalysis

WK An, SJ Zheng, YN Du, SY Ding, ZJ Li… - Catalysis Science & …, 2020 - pubs.rsc.org
Various photoactive building blocks can be incorporated into porous organic polymers
(POPs). The intrinsic properties, such as various synthetic methods, outstanding inherent …

The mechanochemical Scholl reaction as a versatile synthesis tool for the solvent-free generation of microporous polymers

A Krusenbaum, S Grätz, S Bimmermann, S Hutsch… - RSC …, 2020 - pubs.rsc.org
Herein we report the mechanochemical Scholl polymerization of 1, 3, 5-triphenylbenzene in
a high speed ball mill. The reaction is conducted solvent-free, solely using solid FeCl3. The …

Scalable and sustainable synthesis of advanced porous materials

SB Peh, Y Wang, D Zhao - ACS Sustainable Chemistry & …, 2019 - ACS Publications
Advanced porous materials (APMs) constructed from structure-encoded building blocks
present an unprecedented degree for molecular design, and have demonstrated class …

The mechanochemical Friedel‐Crafts polymerization as a solvent‐free cross‐linking approach toward microporous polymers

A Krusenbaum, J Geisler, FJL Kraus… - Journal of Polymer …, 2022 - Wiley Online Library
Herein we report the mechanochemical Friedel‐Crafts alkylation of 1, 3, 5‐triphenylbenzene
(TPB) with two organochloride cross‐linking agents, dichloromethane (DCM) and chloroform …