Metal‐catalyzed cross‐coupling reactions belong to the most important transformations in
organic synthesis. Copper catalysis has received great attention owing to the low toxicity …

Understanding the mechanisms of chemical reactions, especially catalysis, has been an
important and active area of computational organic chemistry, and close collaborations …

Cu-mediated Ullmann-type cross-coupling has experienced significant advances over the
last century since the seminal publication by Ullmann in 1901. These advances have …

Covalent organic frameworks (COFs) have received broad interest owing to their permanent
porosity, high stability, and tunable functionalities. COFs with long‐range π‐conjugation and …

Ullmann-type C–N coupling reactions represent an important alternative to well-established
Pd-catalyzed approaches due to the differing reactivity and the lower cost of Cu. While the …

Dialkylbiaryl phosphines are a valuable class of ligand for Pd-catalyzed amination reactions
and have been applied in a range of contexts. This perspective attempts to aid the reader in …

The C–N cross-coupling chemistry intensely developed since the late 1990s has supplied
synthesists with an overwhelming number of methods to effectively combine carbon and …

The utility of copper-mediated cross-coupling reactions has been significantly increased by
the development of mild reaction conditions and the ability to employ catalytic amounts of …

Major new advances in synthetic chemistry methods are typically reported using simple, non-
standardized reaction substrates, and reaction failures are rarely documented. This makes …

Lewis base adducts of tetra‐alkoxy diboron compounds, in particular bis (pinacolato)
diboron (B2pin2), have been proposed as the active source of nucleophilic boryl species in …