Molecular complexes formed by halides of group 4, 5, 13–15 elements and the thermodynamic characteristics of their vaporization and dissociation found by the static …
EI Davydova, TN Sevastianova, AV Suvorov… - Coordination Chemistry …, 2010 - Elsevier
Donor–acceptor molecular complexes (adducts ADx) play important role in modern
technology. They are prospective single-source precursors for the synthesis of solid phases …
technology. They are prospective single-source precursors for the synthesis of solid phases …
Coordination chemistry of dialkylcyanamides: Binding properties, synthesis of metal complexes, and ligand reactivity
NA Bokach, VY Kukushkin - Coordination Chemistry Reviews, 2013 - Elsevier
Activation of conventional NCR nitriles (R= Alk, Ar) by their ligation to metal centers has
been intensively studied in recent decades. By contrast, the chemistry of dialkylcyanamides …
been intensively studied in recent decades. By contrast, the chemistry of dialkylcyanamides …
[HTML][HTML] The reactivity of halides of high valent groups 5 and 6 metals with oxygen and nitrogen organic donors and the parallelism with related chemistry of main …
Homoleptic halides of high-valent transition metals are acidic species possessing a strong
affinity to N-and O-donors. The formation of coordination adducts with related organic …
affinity to N-and O-donors. The formation of coordination adducts with related organic …
Novel (cyanamide) Zn II complexes and zinc (ii)-mediated hydration of the cyanamide ligands
AS Smirnov, ES Butukhanova, NA Bokach… - Dalton …, 2014 - pubs.rsc.org
The cyanamides NCNR2 (R2= Me2, Ph2, C5H10) react with ZnX2 (X= Cl, Br, I) in a 2: 1
molar ratio at RT, giving a family of zinc (II) complexes [ZnX2 (NCNR2) 2](R2= Me2, X= Cl 1 …
molar ratio at RT, giving a family of zinc (II) complexes [ZnX2 (NCNR2) 2](R2= Me2, X= Cl 1 …
Pnictogen bonding in pyrazine•PnX5 (Pn = P, As, Sb and X = F, Cl, Br) complexes
J Fanfrlík, W Zierkiewicz, P Švec, Z Růžičková… - Journal of Molecular …, 2017 - Springer
This paper presents a study of pnictogen bonding in a series of pyrazine• PnX 5 (Pn= P, As,
Sb and X= F, Cl, Br) complexes. The whole series was studied computationally. Moreover …
Sb and X= F, Cl, Br) complexes. The whole series was studied computationally. Moreover …
Amino‐substituted 2‐Azaallenium Salts
JC Jochims, R Abu‐El‐Halawa, I Jibril… - Chemische …, 1984 - Wiley Online Library
Abstract Nitrilium salts (14a–i) react with imines (15a–e) to afford the mono‐to tetraaza‐
substituted 2‐azaallenium salts 16a–w in high yields. The stereochemistry of these …
substituted 2‐azaallenium salts 16a–w in high yields. The stereochemistry of these …
Lewis acidity of Ph2SbX3, where X= Cl or Br. Crystal structures of Ph2SbCl3· H2O and Ph2SbBr3· MeCN
TT Bamgboye, MJ Begley, DB Sowerby - Journal of Organometallic …, 1989 - Elsevier
Diphenylantimony trichloride and tribromide are weak Lewis acids forming 1 1 addition
compounds with acetonitrile which rapidly lose coordinated nitrile at room temperature. The …
compounds with acetonitrile which rapidly lose coordinated nitrile at room temperature. The …
Synthesis and structure of tetraphenylantimony cyanamide
IV Egorova, VV Zhidkov, IP Grinishak… - Russian Journal of …, 2014 - Springer
The reactions of tetraphenylantimony chloride and bromide with carbamide were used to
obtain tetraphenylantimony cyanamide in yields of 52 and 48%, respectively. According to X …
obtain tetraphenylantimony cyanamide in yields of 52 and 48%, respectively. According to X …
Structures of molecular complexes of SbCl5 with pyridine and acetonitrile: equal bond lengths, different stability
Molecular structure of crystalline complex SbCl 5• Py was determined for the first time and
the structure of the complex SbCl 5• AN was refined by means of single crystal X-ray …
the structure of the complex SbCl 5• AN was refined by means of single crystal X-ray …
Highly Reactive NiII‐Bound Nitrile–Oxime Coupling Intermediates Stabilized by Substituting Conventional Nitriles with a Dialkylcyanamide
EV Andrusenko, EV Kabin, AS Novikov… - European Journal of …, 2015 - Wiley Online Library
Nickel (II)‐mediated coupling between the cyanamide Me2NCN and the ketoximes Me (R)
C= NOH (R= Me, Ph) gives chelates of the general formula [NiClx (H2O) y {HN= C …
C= NOH (R= Me, Ph) gives chelates of the general formula [NiClx (H2O) y {HN= C …