Functional supramolecular systems: Design and applications

IS Antipin, MV Alfimov, VV Arslanov… - Russian Chemical …, 2021 - iopscience.iop.org
The interest in functional supramolecular systems for the design of innovative materials and
technologies, able to fundamentally change the world, is growing at a high pace. The huge …

Strategies for binding multiple guests in metal–organic cages

FJ Rizzuto, LKS von Krbek, JR Nitschke - Nature Reviews Chemistry, 2019 - nature.com
The binding of multiple guests by a single entity can lead to new modes of host–guest
interactions and thus new applications in, for example, catalysis and sensing. With the aim of …

Mixed-ligand metal–organic frameworks and heteroleptic coordination cages as multifunctional scaffolds—a comparison

S Pullen, GH Clever - Accounts of Chemical Research, 2018 - ACS Publications
Conspectus Porous nanostructures and materials based on metal-mediated self-assembly
have developed into a vibrantly studied subdiscipline of supramolecular chemistry during …

Bent anthracene dimers as versatile building blocks for supramolecular capsules

M Yoshizawa, L Catti - Accounts of chemical research, 2019 - ACS Publications
Conspectus This Account provides a comprehensive summary of our 1-decade-long
investigations into bent anthracene dimers as versatile building blocks for supramolecular …

Structural chemistry of giant metal based supramolecules

AV Virovets, E Peresypkina, M Scheer - Chemical Reviews, 2021 - ACS Publications
The review presents a bird-eye view on the state of research in the field of giant
nonbiological discrete metal complexes and ions of nanometer size, which are structurally …

The promise of self-assembled 3D supramolecular coordination complexes for biomedical applications

A Casini, B Woods, M Wenzel - Inorganic Chemistry, 2017 - ACS Publications
In the supramolecular chemistry field, coordination-driven self-assembly has provided the
basis for tremendous growth across many subdisciplines, spanning from fundamental …

Identification of a Heteroleptic Pd6L6L′6 Coordination Cage by Screening of a Virtual Combinatorial Library

S Sudan, RJ Li, SM Jansze, A Platzek… - Journal of the …, 2021 - ACS Publications
The design of structurally defined heteroleptic coordination cages is a challenging task, and
only few examples are known to date. Here we describe a selection approach that allowed …

Pseudo‐heterolepticity in Low‐Symmetry Metal‐Organic Cages

JEM Lewis - Angewandte Chemie, 2022 - Wiley Online Library
Heteroleptic metal‐organic cages, formed through integrative self‐assembly of ligand
mixtures, are highly attractive as reduced symmetry supramolecular hosts. Ensuring high …

Dynamic Metallosupramolecular Cages Containing 12 Adaptable Pockets for High-Order Guest Binding Beyond Biomimicry

YH Huang, YL Lu, J Ruan, SP Zheng… - Journal of the …, 2023 - ACS Publications
Molecular recognition lies at the heart of biological functions, which inspires lasting research
in artificial host syntheses to mimic biomolecules that can recognize, process, and transport …

Heterotrimetallic double cavity cages: syntheses and selective guest binding

LS Lisboa, D Preston, CJ McAdam… - Angewandte Chemie …, 2022 - Wiley Online Library
A strategy for the generation of heterotrimetallic double cavity (DC) cages [PdnPtmL4]
6+(DC1: n= 1, m= 2; and DC2: n= 2, m= 1) is reported. The DC cages were generated by …