First-row d-block element-catalyzed carbon–boron bond formation and related processes

SK Bose, L Mao, L Kuehn, U Radius… - Chemical …, 2021 - ACS Publications
Organoboron reagents represent a unique class of compounds because of their utility in
modern synthetic organic chemistry, often affording unprecedented reactivity. The …

Photoinduced activation of alkyl chlorides

CL Ji, X Zhai, QY Fang, C Zhu, J Han… - Chemical Society Reviews, 2023 - pubs.rsc.org
In recent years, the activation of unactivated alkyl chlorides through light-induced processes
has emerged as a promising field in radical chemistry, and has led to new transformations in …

[HTML][HTML] Plasmonic heterogeneous catalysis for organic transformations

J Zhao, J Wang, AJ Brock, H Zhu - Journal of Photochemistry and …, 2022 - Elsevier
Plasmonic catalysis has been recognised as a promising alternative to many conventional
thermal catalytic processes in organic synthesis. In addition to their high activity in fine …

Light-induced borylation: developments and mechanistic insights

D Lai, S Ghosh, A Hajra - Organic & Biomolecular Chemistry, 2021 - pubs.rsc.org
Organoboron compounds are very important derivatives because of their profound impacts
on medicinal, biological as well as industrial applications. The development of several novel …

[HTML][HTML] Dinuclear gold-catalyzed divergent dechlorinative radical borylation of gem-dichloroalkanes

CL Ji, H Chen, Q Gao, J Han, W Li, J Xie - Nature Communications, 2024 - nature.com
The enormous and widespread use of organoboronic acids has prompted the development
of innovative synthetic methodologies to meet the demands on structural diversity and …

Chlorine atom transfer of unactivated alkyl chlorides enabled by zirconocene and photoredox catalysis

T Okita, K Aida, K Tanaka, E Ota… - Precision Chemistry, 2023 - ACS Publications
Alkyl chlorides are robust precursors to carbon radicals; however, their relative inertness has
hampered their practical use. Although modern photochemical strategies have greatly …

Synthesis of Alkyl and Aryl Boronate Esters via CeO2-Catalyzed Borylation of Alkyl and Aryl Electrophiles Including Alkyl Chlorides

R Bhawar, S Saini, KS Patil… - The Journal of Organic …, 2023 - ACS Publications
A recyclable protocol using a CeO2-nanorod catalyst for borylation of alkyl halides with
B2pin2 (pin= OCMe2CMe2O) is reported. A wide range of synthetically useful alkyl boronate …

Metal‐Organic Frameworks for Catalytic Construction of C− B Bond and Related Reactions

A Prakash, S Saini, S Basappa, DK Gupta… - …, 2023 - Wiley Online Library
Organoboranes are important reagents in modern synthetic organic chemistry. The C− B
bonds presented in these derivatives are transformable into a C− X (X= C, N, O, and …

Boosting hot electrons transfer via laser-induced atomic redistribution for plasmon-enhanced nitroreduction and single-particle study

F Tong, C Cui, X Liang, Z Wang, Y Liu, P Wang… - Journal of …, 2022 - Elsevier
Plasmonic nanostructures with strong light absorption and high catalytic activity are ideal
platform to realize efficient light-driven catalysis. This work developed a laser-induced …

PtCu Alloy-Modified Triptycene-Based Polymer with Charge Separation for Photocatalytic Hydrogen Evolution from Water/Seawater

J Zhang, X Li, Z Peng, X Deng, Y Wang, Z Li… - Inorganic …, 2024 - ACS Publications
Direct photocatalytic hydrogen from earth-abundant seawater is a great potential way to
achieve sustainable and clean energy, yet unsatisfactory decomposition and rapid electron …