Ligand configurational entropy and protein binding

CA Chang, W Chen, MK Gilson - Proceedings of the …, 2007 - National Acad Sciences
The restriction of a small molecule's motion on binding to a protein causes a loss of
configurational entropy, and thus a penalty in binding affinity. Some energy models used in …

A thermodynamic framework for understanding temperature sensing by transient receptor potential (TRP) channels

DE Clapham, C Miller - Proceedings of the National …, 2011 - National Acad Sciences
The exceptionally high temperature sensitivity of certain transient receptor potential (TRP)
family ion channels is the molecular basis of hot and cold sensation in sensory neurons. The …

Ionic liquids: first direct determination of their cohesive energy

LM Santos, JN Canongia Lopes… - Journal of the …, 2007 - ACS Publications
Molar enthalpies of vaporization, of a homologous series of 1-alkyl-3-methylimidazolium bis
(trifluoromethyl sulfonyl) imides,[C n mim][NTf2],(with 2≤ n≤ 8) were directly determined for …

High-Accuracy Vapor Pressure Data of the Extended [CnC1im][Ntf2] Ionic Liquid Series: Trend Changes and Structural Shifts

MAA Rocha, CF Lima, LR Gomes… - The Journal of …, 2011 - ACS Publications
For the first time, two distinct trends are clearly evidenced for the enthalpies and entropies of
vaporization along the [C n mim][Ntf2] ILs series. The trend shifts observed for Δlg H mo and …

Thermodynamics of cationic lipid binding to DNA and DNA condensation: roles of electrostatics and hydrophobicity

D Matulis, I Rouzina, VA Bloomfield - Journal of the American …, 2002 - ACS Publications
Alkylammonium binding to DNA was studied by isothermal titration calorimetry.
Experimental data, obtained as functions of alkyl chain length, salt concentration, DNA …

The Hildebrand solubility parameters, cohesive energy densities and internal energies of 1-alkyl-3-methylimidazolium-based room temperature ionic liquids

SH Lee, SB Lee - Chemical communications, 2005 - pubs.rsc.org
The Hildebrand solubility parameters, cohesive energy densities and internal energies of 1-alkyl-3-methylimidazolium-based
room temperature ionic liqu ... - Chemical Communications (RSC Publishing) DOI:10.1039/B503740A …

The hydrophobic effect: is water afraid, or just not that interested?

TP Silverstein - ChemTexts, 2020 - Springer
Our understanding of the hydrophobic effect has advanced greatly since 1990, with the help
of experimental, theoretical, and computer simulation results. The key hydrophobic signature …

Viscoelastic diamine surfactant for stable carbon dioxide/water foams over a wide range in salinity and temperature

AS Elhag, C Da, Y Chen, N Mukherjee… - Journal of colloid and …, 2018 - Elsevier
Hypothesis The viscosity and stability of CO 2/water foams at elevated temperature can be
increased significantly with highly viscoelastic aqueous lamellae. The slow thinning of these …

Influence of ligand shell ordering on dimensional confinement of cesium lead bromide (CsPbBr 3) perovskite nanoplatelets

J Cho, H Jin, DG Sellers, DF Watson, DH Son… - Journal of Materials …, 2017 - pubs.rsc.org
The perovskite cesium lead bromide (CsPbBr3) has emerged as an attractive thermally and
chemically robust alternative to hybrid lead perovskite halides and analogues of this …

Ionic liquids: Dissecting the enthalpies of vaporization

T Köddermann, D Paschek, R Ludwig - ChemPhysChem, 2008 - Wiley Online Library
We calculate the heats of vaporisation for imidazolium‐based ionic liquids [Cnmim][NTf2]
with n= 1, 2, 4, 6, 8 by means of molecular dynamics (MD) simulations and discuss their …