Ligand configurational entropy and protein binding
The restriction of a small molecule's motion on binding to a protein causes a loss of
configurational entropy, and thus a penalty in binding affinity. Some energy models used in …
configurational entropy, and thus a penalty in binding affinity. Some energy models used in …
A thermodynamic framework for understanding temperature sensing by transient receptor potential (TRP) channels
DE Clapham, C Miller - Proceedings of the National …, 2011 - National Acad Sciences
The exceptionally high temperature sensitivity of certain transient receptor potential (TRP)
family ion channels is the molecular basis of hot and cold sensation in sensory neurons. The …
family ion channels is the molecular basis of hot and cold sensation in sensory neurons. The …
Ionic liquids: first direct determination of their cohesive energy
LM Santos, JN Canongia Lopes… - Journal of the …, 2007 - ACS Publications
Molar enthalpies of vaporization, of a homologous series of 1-alkyl-3-methylimidazolium bis
(trifluoromethyl sulfonyl) imides,[C n mim][NTf2],(with 2≤ n≤ 8) were directly determined for …
(trifluoromethyl sulfonyl) imides,[C n mim][NTf2],(with 2≤ n≤ 8) were directly determined for …
High-Accuracy Vapor Pressure Data of the Extended [CnC1im][Ntf2] Ionic Liquid Series: Trend Changes and Structural Shifts
For the first time, two distinct trends are clearly evidenced for the enthalpies and entropies of
vaporization along the [C n mim][Ntf2] ILs series. The trend shifts observed for Δlg H mo and …
vaporization along the [C n mim][Ntf2] ILs series. The trend shifts observed for Δlg H mo and …
Thermodynamics of cationic lipid binding to DNA and DNA condensation: roles of electrostatics and hydrophobicity
Alkylammonium binding to DNA was studied by isothermal titration calorimetry.
Experimental data, obtained as functions of alkyl chain length, salt concentration, DNA …
Experimental data, obtained as functions of alkyl chain length, salt concentration, DNA …
The Hildebrand solubility parameters, cohesive energy densities and internal energies of 1-alkyl-3-methylimidazolium-based room temperature ionic liquids
SH Lee, SB Lee - Chemical communications, 2005 - pubs.rsc.org
The Hildebrand solubility parameters, cohesive energy densities and internal energies of 1-alkyl-3-methylimidazolium-based
room temperature ionic liqu ... - Chemical Communications (RSC Publishing) DOI:10.1039/B503740A …
room temperature ionic liqu ... - Chemical Communications (RSC Publishing) DOI:10.1039/B503740A …
The hydrophobic effect: is water afraid, or just not that interested?
TP Silverstein - ChemTexts, 2020 - Springer
Our understanding of the hydrophobic effect has advanced greatly since 1990, with the help
of experimental, theoretical, and computer simulation results. The key hydrophobic signature …
of experimental, theoretical, and computer simulation results. The key hydrophobic signature …
Viscoelastic diamine surfactant for stable carbon dioxide/water foams over a wide range in salinity and temperature
Hypothesis The viscosity and stability of CO 2/water foams at elevated temperature can be
increased significantly with highly viscoelastic aqueous lamellae. The slow thinning of these …
increased significantly with highly viscoelastic aqueous lamellae. The slow thinning of these …
Influence of ligand shell ordering on dimensional confinement of cesium lead bromide (CsPbBr 3) perovskite nanoplatelets
The perovskite cesium lead bromide (CsPbBr3) has emerged as an attractive thermally and
chemically robust alternative to hybrid lead perovskite halides and analogues of this …
chemically robust alternative to hybrid lead perovskite halides and analogues of this …
Ionic liquids: Dissecting the enthalpies of vaporization
We calculate the heats of vaporisation for imidazolium‐based ionic liquids [Cnmim][NTf2]
with n= 1, 2, 4, 6, 8 by means of molecular dynamics (MD) simulations and discuss their …
with n= 1, 2, 4, 6, 8 by means of molecular dynamics (MD) simulations and discuss their …