New strategies for the transition-metal catalyzed synthesis of aliphatic amines

A Trowbridge, SM Walton, MJ Gaunt - Chemical reviews, 2020 - ACS Publications
Transition-metal catalyzed reactions that are able to construct complex aliphatic amines from
simple, readily available feedstocks have become a cornerstone of modern synthetic …

Tandem Hydroaminomethylation reaction to synthesize amines from alkenes

P Kalck, M Urrutigoïty - Chemical Reviews, 2018 - ACS Publications
In the context of atom economy and low environmental impact, synthesis of amines by an
efficient catalytic process is of great importance to produce these building blocks for fine …

Isomerization–hydroformylation tandem reactions

M Vilches-Herrera, L Domke, A Börner - ACS Catalysis, 2014 - ACS Publications
The metal-catalyzed isomerization–hydroformylation tandem reaction is of great importance
for the production of linear aldehydes starting from internal olefins, but also, the shift of the …

Recent advances in aminative difunctionalization of alkenes

Z Wu, M Hu, J Li, W Wu, H Jiang - Organic & Biomolecular Chemistry, 2021 - pubs.rsc.org
Alkenes are versatile building blocks in modern organic synthesis. In the difunctionalization
reactions of alkenes, two functional groups can be simultaneously introduced into the π …

Refining plant oils and sugars to platform chemicals, monomers, and polymers

S Pandey, BS Rajput, SH Chikkali - Green Chemistry, 2021 - pubs.rsc.org
As fossil resources continue to dwindle and environmental concerns are magnified, finding
sustainable alternatives is the only way to mitigate resource availability and derisk the …

Recent progress in rhodium-catalyzed hydroaminomethylation

C Chen, XQ Dong, X Zhang - Organic Chemistry Frontiers, 2016 - pubs.rsc.org
Hydroaminomethylation is a perfect reaction for converting alkenes into valuable amines
with high atom economy in the presence of the syngas and amines. Significant progress has …

Rhodium/Yanphos-Catalyzed Asymmetric Interrupted Intramolecular Hydroaminomethylation of trans-1,2-Disubstituted Alkenes

C Chen, S Jin, Z Zhang, B Wei, H Wang… - Journal of the …, 2016 - ACS Publications
The first interrupted asymmetric hydroaminomethylation reaction was developed. The
challenging trans-1, 2-disubstituted olefins were employed as substrates, and a series of …

Recent advances in catalytic C–N bond formation: a comparison of cascade hydroaminomethylation and reductive amination reactions with the corresponding …

S Raoufmoghaddam - Organic & Biomolecular Chemistry, 2014 - pubs.rsc.org
The design and catalytic implementation of tandem reactions to selectively create nitrogen-
containing products under mild conditions has encountered numerous challenges in …

Efficient and regioselective ruthenium-catalyzed hydro-aminomethylation of olefins

L Wu, I Fleischer, R Jackstell… - Journal of the American …, 2013 - ACS Publications
An efficient and regioselective ruthenium-catalyzed hydroaminomethlyation of olefins is
reported. Key to success is the use of specific 2-phosphino-substituted imidazole ligands …

A Multicatalytic Approach to the Hydroaminomethylation of α‐Olefins

S Hanna, JC Holder, JF Hartwig - Angewandte Chemie, 2019 - Wiley Online Library
We report an approach to conducting the hydroaminomethylation of diverse α‐olefins with a
wide range of alkyl, aryl, and heteroarylamines at relatively low temperatures (70–80° C) …