Mechanically interlocked polymers based on rotaxanes

L Chen, X Sheng, G Li, F Huang - Chemical Society Reviews, 2022 - pubs.rsc.org
The nature of mechanically interlocked molecules (MIMs) has continued to encourage
researchers to design and construct a variety of high-performance materials. Introducing …

Material properties and applications of mechanically interlocked polymers

LF Hart, JE Hertzog, PM Rauscher, BW Rawe… - Nature Reviews …, 2021 - nature.com
Mechanically interlocked polymers (MIPs), such as polyrotaxanes and polycatenanes, are
polymer architectures that incorporate a mechanical bond. In a polyrotaxane, the …

Development of pseudorotaxanes and rotaxanes: from synthesis to stimuli-responsive motions to applications

M Xue, Y Yang, X Chi, X Yan, F Huang - Chemical reviews, 2015 - ACS Publications
The history of isomeric types of organic molecules has passed through several important
stages:(1) Molecules that differ from each other with different numbers and types of atoms;(2) …

Dynamic imine chemistry

ME Belowich, JF Stoddart - Chemical Society Reviews, 2012 - pubs.rsc.org
Formation of an imine—from an amine and an aldehyde—is a reversible reaction which
operates under thermodynamic control such that the formation of kinetically competitive …

The story of the little blue box: a tribute to Siegfried Hünig

XY Chen, H Chen… - Angewandte Chemie …, 2023 - Wiley Online Library
The tetracationic cyclophane, cyclobis (paraquat‐p‐phenylene), also known as the little blue
box, constitutes a modular receptor that has facilitated the discovery of many host–guest …

The rise and promise of molecular nanotopology

QH Guo, Y Jiao, Y Feng, JF Stoddart - CCS Chemistry, 2021 - chinesechemsoc.org
Molecular nanotopology—a term we coined recently—is a rapidly developing field of
research that is emerging out of the confluence of chemical topology with the mechanical …

Recent developments in polypseudorotaxanes and polyrotaxanes

M Arunachalam, HW Gibson - Progress in Polymer Science, 2014 - Elsevier
This review highlights developments since 2008 in the field of polypseudorotaxanes and
polyrotaxanes. Progress in synthetic polyrotaxane chemistry has resulted in the preparation …

Solution-phase mechanistic study and solid-state structure of a tris (bipyridinium radical cation) inclusion complex

AC Fahrenbach, JC Barnes… - Journal of the …, 2012 - ACS Publications
The ability of the diradical dicationic cyclobis (paraquat-p-phenylene)(CBPQT2 (•+)) ring to
form inclusion complexes with 1, 1′-dialkyl-4, 4′-bipyridinium radical cationic (BIPY•+) …

Mechanically interlocked molecules assembled by π–π recognition

G Barin, A Coskun, MMG Fouda, JF Stoddart - ChemPlusChem, 2012 - Wiley Online Library
The beauty and utility of interlocked architectures have been making their way relentlessly
into chemistry in the form of mechanically interlocked molecules (MIMs) for almost half a …

Synthetic oligorotaxanes exert high forces when folding under mechanical load

D Sluysmans, S Hubert, CJ Bruns, Z Zhu… - Nature …, 2018 - nature.com
Folding is a ubiquitous process that nature uses to control the conformations of its molecular
machines, allowing them to perform chemical and mechanical tasks. Over the years …