Thermal recombinative desorption rates of HD on Pd (111) and Pd (332) are reported from
transient kinetic experiments performed between 523 and 1023 K. A detailed kinetic model …

There is wide interest in developing accurate theories for predicting rates of chemical
reactions that occur at metal surfaces, especially for applications in industrial catalysis …

In this work, we investigate the decomposition dynamics of formate (HCO2), which is an
important reaction intermediate in many catalytic processes, on three model catalyst …

The field of Molecular Scattering is reviewed as it pertains to gas-gas as well as gas-surface
chemical reaction dynamics. We emphasize the importance of collaboration of experiment …

We combine velocity map imaging (VMI) with temperature-programmed desorption (TPD)
experiments to record the angular-resolved velocity distributions of recombinatively …

The final CO2 formation step in the decomposition of deuterated formic acid (DCOOH) on Pt
surfaces is investigated using density functional theory (DFT) and ab initio molecular …

Velocity-resolved kinetics is used to measure the thermal rate of formic acid desorption from
Pd (111) between 228 and 273 K for four isotopologues: HCOOH, HCOOD, DCOOH …

Uncovering the role of reaction intermediates is crucial to developing an understanding of
heterogeneous catalysis because catalytic reactions often involve complex networks of …

This study presents velocity-resolved desorption experiments of recombinatively-desorbing
oxygen from Ag (111). We combine molecular beam techniques, ion imaging, and …

Most experimental methods for studying the kinetics of surface reactions–for example,
temperature programmed desorption (TPD), molecular beam relaxation spectrometry …