The synthesis and the design of octahedral stereogenic-at-metal complexes featuring chiral
ligands and their application as chiral catalysts in various asymmetric reactions are …

A series of manganese (I) carbonyl complexes bearing structurally related NN-and NNN-
chelating ligands have been synthesized and assessed as catalysts for transfer …

RuCl2 (P–OP)(N–N) complexes (1) containing an atropisomerizable phosphine–phosphite
(P–OP) and a chiral C2 symmetric diamine (N–N) are readily prepared as trans isomers by …

A chemo‐and biocatalytic cascade approach was applied for the stereoselective synthesis
of hydroxy ketones and the corresponding 1, 3‐diols. A new class of tridentate N, N, O …

The synthesis of a small library of 8-substituted 2-methyl-5, 6, 7, 8-tetrahydroquinoline
derivatives is presented. All the compounds were tested for their antiproliferative activity in …

The reaction between an atropoisomeric diphosphine, Bitianp and [Ni (CO) 4] was achieved
by direct condensation in CH 3 Cl to afford complexes of general formula [Ni (CO) 2 …

Os resultados apresentados neste trabalho envolvem a síntese de compostos de
coordenação contendo fosfinas e ligantes redox ativos (ligantes não-inocentes) na esfera …

The main target of this thesis was the investigation of different aspects of the chirality at the
metal centre. In particular we studied stereo-specific synthesis of octahedral transition …