Computational molecular spectroscopy

V Barone, S Alessandrini, M Biczysko… - Nature Reviews …, 2021 - nature.com
Spectroscopic techniques can probe molecular systems non-invasively and investigate their
structure, properties and dynamics in different environments and physico-chemical …

Connections between the accuracy of rotational constants and equilibrium molecular structures

C Puzzarini, JF Stanton - Physical Chemistry Chemical Physics, 2023 - pubs.rsc.org
Rotational spectroscopy is the technique of choice for investigating molecular structures in
the gas phase. Indeed, rotational constants are strongly connected to the geometry of the …

Accuracy and interpretability: The devil and the holy grail. New routes across old boundaries in computational spectroscopy

C Puzzarini, J Bloino, N Tasinato, V Barone - Chemical reviews, 2019 - ACS Publications
The past decade has witnessed an increasing interaction between experiment and theory in
the field of molecular spectroscopy. On the computational side, ongoing developments of …

Benchmark Structures and Conformational Landscapes of Amino Acids in the Gas Phase: a Joint Venture of Machine Learning, Quantum Chemistry, and Rotational …

V Barone, M Fusè, F Lazzari… - Journal of Chemical …, 2023 - ACS Publications
The accurate characterization of prototypical bricks of life can strongly benefit from the
integration of high resolution spectroscopy and quantum mechanical computations. We …

Extension of the “cheap” composite approach to noncovalent interactions: The jun-ChS scheme

S Alessandrini, V Barone… - Journal of chemical theory …, 2019 - ACS Publications
A new variant of the so-called “cheap” composite scheme has been purposely developed for
the evaluation of the interaction energy of noncovalent molecular complexes, with its various …

[图书][B] Tautomerism: methods and theories

L Antonov - 2013 - books.google.com
Covering the gap between basic textbooks and over-specialized scientific publications, this
is the first reference available to describe this interdisciplinary topic for PhD students and …

Neutral peptides in the gas phase: conformation and aggregation issues

E Gloaguen, M Mons, K Schwing… - Chemical Reviews, 2020 - ACS Publications
Combined IR and UV laser spectroscopic techniques in molecular beams merged with
theoretical approaches have proven to be an ideal tool to elucidate intrinsic structural …

Toward spectroscopic accuracy for the structures of large molecules at DFT cost: Refinement and extension of the nano-LEGO approach

V Barone, G Ceselin, F Lazzari… - The Journal of Physical …, 2023 - ACS Publications
The SE100 database collecting accurate equilibrium geometries of medium size molecules
obtained by the semiexperimental (SE) approach has been extended to species containing …

The gas-phase structure of alanine

S Blanco, A Lesarri, JC López… - Journal of the American …, 2004 - ACS Publications
The jet-cooled rotational spectrum of neutral alanine has been studied using laser-ablation
molecular-beam Fourier transform microwave spectroscopy (LA-MB-FTMW). The spectra of …

Diving for accurate structures in the ocean of molecular systems with the help of spectroscopy and quantum chemistry

C Puzzarini, V Barone - Accounts of chemical research, 2018 - ACS Publications
Conspectus The prediction and interpretation of structural properties are the starting points
for a deep understanding of thermochemistry, kinetics, and spectroscopic signatures of …