Chemomechanics of rechargeable batteries: status, theories, and perspectives

LS de Vasconcelos, R Xu, Z Xu, J Zhang… - Chemical …, 2022 - ACS Publications
Chemomechanics is an old subject, yet its importance has been revived in rechargeable
batteries where the mechanical energy and damage associated with redox reactions can …

Challenges and recent advances in high capacity Li‐rich cathode materials for high energy density lithium‐ion batteries

W He, W Guo, H Wu, L Lin, Q Liu, X Han… - Advanced …, 2021 - Wiley Online Library
Li‐rich cathode materials have attracted increasing attention because of their high reversible
discharge capacity (> 250 mA hg− 1), which originates from transition metal (TM) ion redox …

Compositionally complex doping for zero-strain zero-cobalt layered cathodes

R Zhang, C Wang, P Zou, R Lin, L Ma, L Yin, T Li, W Xu… - Nature, 2022 - nature.com
The high volatility of the price of cobalt and the geopolitical limitations of cobalt mining have
made the elimination of Co a pressing need for the automotive industry. Owing to their high …

Crystalline lattice‐confined atomic Pt in metal carbides to match electronic structures and hydrogen evolution behaviors of platinum

T Ma, H Cao, S Li, S Cao, Z Zhao, Z Wu… - Advanced …, 2022 - Wiley Online Library
Platinum‐based catalysts occupy a pivotal position in diverse catalytic applications in
hydrogen chemistry and electrochemistry, for instance, the hydrogen evolution reactions …

Activating lattice oxygen in layered lithium oxides through cation vacancies for enhanced urea electrolysis

WK Han, JX Wei, K Xiao, T Ouyang, X Peng… - Angewandte …, 2022 - Wiley Online Library
Despite the fact that high‐valent nickel‐based oxides exhibit promising catalytic activity for
the urea oxidation reaction (UOR), the fundamental questions concerning the origin of the …

Oxide cathodes: functions, instabilities, self healing, and degradation mitigations

Y Dong, J Li - Chemical Reviews, 2022 - ACS Publications
Recent progress in high-energy-density oxide cathodes for lithium-ion batteries has pushed
the limits of lithium usage and accessible redox couples. It often invokes hybrid anion-and …

Surface enrichment and diffusion enabling gradient-doping and coating of Ni-rich cathode toward Li-ion batteries

H Yu, Y Cao, L Chen, Y Hu, X Duan, S Dai, C Li… - Nature …, 2021 - nature.com
Critical barriers to layered Ni-rich cathode commercialisation include their rapid capacity
fading and thermal runaway from crystal disintegration and their interfacial instability …

A reflection on lithium-ion battery cathode chemistry

A Manthiram - Nature communications, 2020 - nature.com
Lithium-ion batteries have aided the portable electronics revolution for nearly three decades.
They are now enabling vehicle electrification and beginning to enter the utility industry. The …

Assessing the Intrinsic Roles of Key Dopant Elements in High‐Nickel Layered Oxide Cathodes in Lithium‐Based Batteries

Z Cui, Z Guo, A Manthiram - Advanced Energy Materials, 2023 - Wiley Online Library
A rational compositional design is critical for utilizing LiNiO2‐based cathodes with Ni
contents> 90% as promising next‐generation cathode materials. Unfortunately, the lack of a …

High‐Entropy Surface Complex Stabilized LiCoO2 Cathode

X Tan, Y Zhang, S Xu, P Yang, T Liu… - Advanced Energy …, 2023 - Wiley Online Library
Elevating the charge voltage of LiCoO2 increases the energy density of batteries, which is
highly enticing in energy storage implementation ranging from portable electronics to e …