Topological motifs in cyanometallates: from building units to three-periodic frameworks

EV Alexandrov, AV Virovets, VA Blatov… - Chemical …, 2015 - ACS Publications
This review focuses on topological features of three-periodic (framework) p, d, and f metal
cyano complexes or cyanometallates, ie coordination compounds, where CN–ligands play …

Chalcogenide clusters of Group 5–7 metals

VE Fedorov, YV Mironov, NG Naumov… - Russian Chemical …, 2007 - iopscience.iop.org
The state-of-the-art and prospects of the development of chemistry of chalcogenide clusters
of Group 5–7 metals of the Periodic Table are discussed. The main structural types, methods …

Photogeneration of hydrogen from water by hybrid molybdenum sulfide clusters immobilized on titania

D Recatalá, R Llusar, AL Gushchin… - …, 2015 - Wiley Online Library
Two new hybrid molybdenum (IV) Mo3S7 cluster complexes derivatized with diimino ligands
have been prepared by replacement of the two bromine atoms of [Mo3S7Br6] 2− by a …

[HTML][HTML] Trinuclear molybdenum cluster sulfides coordinated to dithiolene ligands and their use in the development of molecular conductors

R Llusar, C Vicent - Coordination Chemistry Reviews, 2010 - Elsevier
The present article reviews synthetic approaches to efficiently prepare Mo3S7 clusters
coordinated to 1, 2-bis-dithiolene ligands of general formula [Mo3S7 (dithiolene) 3] 2 …

Titanium phosphonate oxo-alkoxide “clusters”: solution stability and facile hydrolytic transformation into nano titania

FG Svensson, G Daniel, CW Tai, GA Seisenbaeva… - RSC …, 2020 - pubs.rsc.org
Titanium (oxo-) alkoxide phosphonate complexes were synthesized using different titanium
precursors and tert-butylphosphonic acid (tBPA) as molecular models for interaction …

Synthesis and optical power limiting properties of heteroleptic Mo 3 S 7 clusters

D Recatalá, R Llusar, A Barlow, G Wang… - Dalton …, 2015 - pubs.rsc.org
Substitution of the halide ligands in (Bu4N) 2 [Mo3S7X6](X= Cl, Br) by diimine ligands, such
as 4, 4′-dimethyl-2, 2′-bipyridine (dmbpy), 2, 2′-bipyridine (bpy) and 1, 10 …

Synthesis and Characterization of Mixed Chalcogen Triangular Complexes with New Mo33-S)(μ2-Se2)34+ and M33-S)(μ2-Se)34+(M = Mo, W) …

AL Gushchin, BL Ooi, P Harris, C Vicent… - Inorganic …, 2009 - ACS Publications
In our pursuit of mixed chalcogen-bridged cluster complexes, solids of the compositions
Mo3SSe6Br4 and W3SSe6Br4 were prepared using high-temperature synthesis from the …

Mo3Q7 (Q = S, Se) Clusters Containing Dithiolate/Diselenolate Ligands: Synthesis, Structures, and Their Use as Precursors of Magnetic Single‐Component …

AL Gushchin, R Llusar, C Vicent… - European Journal of …, 2013 - Wiley Online Library
The coordination chemistry of dithiolene and diselenolene ligands towards the all‐selenium
[Mo3Se7Br6] 2–dianion has been investigated. Complexes (nBu4N) 2 [Zn (dmit) 2](dmit= 1 …

[HTML][HTML] Халькогенидные кластеры металлов 5–7 групп

ВЕ Федоров, ЮВ Миронов, НГ Наумов… - Russian Chemical …, 2007 - uspkhim.ru
Аннотация Проанализированы современное состояние и перспективы развития химии
халькогенидных кластеров металлов 5–7 групп Периодической системы. Рассмотрены …

[HTML][HTML] Metal clusters. As they were born in Siberia

V Fedorov - Journal of Cluster Science, 2015 - Springer
Key results of the researches in the field of cluster chemistry executed by scientists of
Nikolaev Institute of Inorganic Chemistry (NIIC) of the Siberian Branch of Russian Academy …