Reaction dynamics studied via femtosecond X-ray liquidography at X-ray free-electron lasers

EH Choi, Y Lee, J Heo, H Ihee - Chemical Science, 2022 - pubs.rsc.org
X-ray free-electron lasers (XFELs) provide femtosecond X-ray pulses suitable for pump–
probe time-resolved studies with a femtosecond time resolution. Since the advent of the first …

Direct observation of bond formation in solution with femtosecond X-ray scattering

KH Kim, JG Kim, S Nozawa, T Sato, KY Oang, TW Kim… - Nature, 2015 - nature.com
The making and breaking of atomic bonds are essential processes in chemical reactions.
Although the ultrafast dynamics of bond breaking have been studied intensively using time …

Structural dynamics of proteins explored via time-resolved x-ray liquidography

Y Lee, H Lee, H Ihee - Chemical Physics Reviews, 2022 - pubs.aip.org
The structure of a protein is closely related to its biological function. In this regard, structural
changes, as well as static structures, have been scrutinized as essential elements in …

Tracking the picosecond deactivation dynamics of a photoexcited iron carbene complex by time-resolved X-ray scattering

D Leshchev, TCB Harlang, LA Fredin, D Khakhulin… - Chemical …, 2018 - pubs.rsc.org
Recent years have seen the development of new iron-centered N-heterocyclic carbene
(NHC) complexes for solar energy applications. Compared to typical ligand systems, the …

Eliminating finite-size effects on the calculation of x-ray scattering from molecular dynamics simulations

AO Dohn, V Markmann, A Nimmrich… - The Journal of …, 2023 - pubs.aip.org
Structural studies using x-ray scattering methods for investigating molecules in solution are
shifting focus toward describing the role and effects of the surrounding solvent. However …

Determining the charge distribution and the direction of bond cleavage with femtosecond anisotropic x-ray liquidography

J Heo, JG Kim, EH Choi, H Ki, DS Ahn, J Kim… - Nature …, 2022 - nature.com
Energy, structure, and charge are fundamental quantities characterizing a molecule.
Whereas the energy flow and structure change in chemical reactions are experimentally …

Filming ultrafast roaming-mediated isomerization of bismuth triiodide in solution

EH Choi, JG Kim, J Kim, H Ki, Y Lee, S Lee… - Nature …, 2021 - nature.com
Roaming reaction, defined as a reaction yielding products via reorientational motion in the
long-range region (3–8 Å) of the potential, is a relatively recently proposed reaction pathway …

Rebuilding the vibrational wavepacket in TRAS using attosecond X-ray pulses

C Wang, M Gong, X Zhao, QW Nan, XY Yu… - Communications …, 2024 - nature.com
Time-resolved X-ray photoelectron spectroscopy (TXPS) is a well-established technique to
probe coherent nuclear wavepacket dynamics using both table-top and free-electron-based …

Triiodide Formation Governs Oxidation Mechanism of Tin–Lead Perovskite Solar Cells via A-Site Choice

A Alsulami, L Lanzetta… - Journal of the …, 2024 - ACS Publications
Mixed tin–lead (Sn–Pb) halide perovskites stand out as promising materials for next-
generation photovoltaics and near-infrared optoelectronics. However, their sensitivity to …

[HTML][HTML] Photodissociation of aqueous I3− observed with liquid-phase ultrafast mega-electron-volt electron diffraction

K Ledbetter, E Biasin, JPF Nunes, M Centurion… - Structural …, 2020 - pubs.aip.org
Developing femtosecond resolution methods for directly observing structural dynamics is
critical to understanding complex photochemical reaction mechanisms in solution. We have …