Molecular metal phosphonates
J Goura, V Chandrasekhar - Chemical reviews, 2015 - ACS Publications
The carboxylate ligand,[RCO 2]−, is one of the most versatile and hence also one of the most
ubiquitous ligands in coordination chemistry.(1-4) Although fairly simple coordination modes …
ubiquitous ligands in coordination chemistry.(1-4) Although fairly simple coordination modes …
Transformations of molecules and secondary building units to materials: a bottom-up approach
R Murugavel, MG Walawalkar, M Dan… - Accounts of chemical …, 2004 - ACS Publications
A variety of complex inorganic solids with open-framework and other fascinating
architectures, involving silicate, phosphate, and other anions, have been synthesized under …
architectures, involving silicate, phosphate, and other anions, have been synthesized under …
Co–Ln mixed-metal phosphonate grids and cages as molecular magnetic refrigerants
YZ Zheng, M Evangelisti, F Tuna… - Journal of the American …, 2012 - ACS Publications
The synthesis, structures, and magnetic properties of six families of cobalt–lanthanide mixed-
metal phosphonate complexes are reported in this Article. These six families can be divided …
metal phosphonate complexes are reported in this Article. These six families can be divided …
Large magnetocaloric effect in a Wells-Dawson type {Ni6Gd 6P6} cage
YZ Zheng, M Evangelisti, REP Winpenny - 2011 - digital.csic.es
Magnetic refrigeration is based on the magnetocaloric effect (MCE) which relies on the
entropy change of a material when placed in a magnetic field. 1 Molecular magnets have …
entropy change of a material when placed in a magnetic field. 1 Molecular magnets have …
Co–Gd phosphonate complexes as magnetic refrigerants
YZ Zheng, M Evangelisti, REP Winpenny - Chemical Science, 2011 - pubs.rsc.org
Three 3d–4f phosphonate complexes,[CoII8GdIII8 (μ3-OH) 4 (NO3) 4 (O3PtBu) 8 (O2CtBu)
16],[CoII8GdIII4 (O3PtBu) 6 (O2CtBu) 16] and [CoII4GdIII6 (O3PCH2Ph) 6 (O2CtBu) 14 …
16],[CoII8GdIII4 (O3PtBu) 6 (O2CtBu) 16] and [CoII4GdIII6 (O3PCH2Ph) 6 (O2CtBu) 14 …
Pyrazoles and pyrazolides—flexible synthons in self-assembly
MA Halcrow - Dalton Transactions, 2009 - pubs.rsc.org
This Perspective summarises the chemistry of the pyrazole ring, and reviews the metal
coordination modes adopted by 1H-pyrazoles and their anions. Pyrazolide anions are …
coordination modes adopted by 1H-pyrazoles and their anions. Pyrazolide anions are …
High-nuclearity paramagnetic 3d-metal complexes with oxygen-and nitrogen-donor ligands
REP Winpenny - Advances in Inorganic Chemistry, 2001 - Elsevier
Publisher Summary This chapter discusses high-nuclearity paramagnetic 3d-metal
complexes with oxygen-and nitrogen-donor ligands. The studies of high-nuclearity iron …
complexes with oxygen-and nitrogen-donor ligands. The studies of high-nuclearity iron …
Synthesis and structural and magnetic characterization of cobalt (II) phosphonate cage compounds
S Langley, M Helliwell, R Sessoli, SJ Teat… - Inorganic …, 2008 - ACS Publications
Reaction of cobalt salts with phosphonic acids in the presence of 6-chloro-2-hydroxypyridine
as a co-ligand, normally in its deprotonated form, leads to a series of new polymetallic cobalt …
as a co-ligand, normally in its deprotonated form, leads to a series of new polymetallic cobalt …
Polymetallic Cobalt and Manganese Cages with Phosphinate and Phosphonate Ligands.
EK Brechin, RA Coxall, A Parkin, S Parsons… - … (International ed. in …, 2001 - europepmc.org
Addition of a coligand in reactions of phosphonates with salts of late 3d metals can lead to
more soluble and tractable materials, such as the {Co 13} cage shown (Co: green; P …
more soluble and tractable materials, such as the {Co 13} cage shown (Co: green; P …
Spontaneous Self-Assembly of an Unsymmetric Trinuclear Triangular Copper(II) Pyrazolate Complex, [Cu3(μ3-OH)(μ-pz)3(MeCOO)2(Hpz)] (Hpz = Pyrazole) …
M Casarin, C Corvaja, C Di Nicola, D Falcomer… - Inorganic …, 2004 - ACS Publications
The almost quantitative formation of the triangular trinuclear copper derivative [Cu3 (μ3-
OH)(μ-pz) 3 (MeCOO) 2 (Hpz)](1)(Hpz= pyrazole), has been simply achieved by adding Hpz …
OH)(μ-pz) 3 (MeCOO) 2 (Hpz)](1)(Hpz= pyrazole), has been simply achieved by adding Hpz …