Since 2016, when simple triethylborane (Et3B) was revealed as a very capable catalyst for
the copolymerization of epoxides and carbon dioxide, research effort regarding this type of …

Cyclic polymers present a topology that differ significantly from their linear counterparts due
to their circular structure and therefore, the lack of chain ends. These simple characteristics …

The development of metal-free catalysts with excellent activity and controllability remains a
significant obstacle for the copolymerization of CO2 and epoxides. In this study, we used the …

Topology control of polymers is critical for determining their physical properties and potential
applications; in particular, topologies that incorporate numerous hydrogen bonding (H …

The synthesis of polyglycidol (or polyglycerol) using tris-(pentafluorophenyl) borane [B (C 6
F 5) 3] as a catalyst produces a branched structure with a cyclic core by a mechanism of …

The topologies of polymers can impact the performance of polymeric materials, including
their chemical and physical properties. In this work, a dynamic covalent bond of boronate …

Comprehensive Summary Efficient synthesis of polyester polyols with tunable molecular
weight and microstructures from cyclic anhydride/epoxide mixtures by taking advantage of …

Control of polymer topologies is essential to determine their unique physical properties and
potential applications. The polymer topologies can have a critical effect on pigment …

In this study, quasilinear polyglycidols (PG) s with ultralow degree of branching (DB) could
be synthesized through anionic polymerization of glycidol carried out in the presence of …

Abstract N‐Heterocyclic olefin (NHO)‐based polymerization pathways for the
copolymerization of ethylene oxide (EO) and propylene oxide (PO) are investigated in detail …