Radical species are significant in modern chemistry. Their unique chemical bonding and
novel physicochemical properties play significant roles not only in fundamental chemistry …

Conspectus Hypervalent iodine reagents find application as selective chemical oxidants in a
diverse array of oxidative transformations. The utility of these reagents is often ascribed to …

Conspectus Since the pioneering work by Thiele and Chichibabin, who synthesized the first
diradicals bridged by phenylene and biphenylene groups in 1904 and 1907, respectively …

Small molecule redox mediators convey interfacial electron transfer events into bulk solution
and can enable diverse substrate activation mechanisms in synthetic electrocatalysis. Here …

The responsive behavior of an entity towards its immediate surrounding is referred to as an
adaptive response. The adaptive responses of a noncovalent interaction at the molecular …

Synthesis of stable main‐group element‐based radicals represents one of the most
interesting topics in contemporary organometallic chemistry, because of their vital roles in …

Phenyl tellurosulfide (PhS-TePh) was used to study the redox activity of the S–Te bond in
lithium batteries. PhS-TePh formed a dynamic covalent network during lithiation, which …

Featuring an extra electron in the π* antibonding orbital, species with a 2‐center‐3‐electron
(2c3e) π bond without an underlying σ bond are scarcely known. Herein, we report the …

A series of bis [N, N‐di‐(4‐methoxylphenyl) amino] arene dications 12+–32+ have been
synthesized and characterized. Their electronic structures were investigated by various …

The one-electron oxidations of 1, 8-chalcogen naphthalenes Nap (SPh) 2 (1) and Nap
(SPh)(SePh)(2) lead to the formation of persistent radical cations 1•+ and 2•+ in solution …