Chirality in adsorption on solid surfaces

F Zaera - Chemical Society Reviews, 2017 - pubs.rsc.org
In the present review we survey the main advances made in recent years on the
understanding of chemical chirality at solid surfaces. Chirality is an important topic, made …

[HTML][HTML] Chirality of molecular nanostructures on surfaces via molecular assembly and reaction: manifestation and control

Y Xu, JJ Duan, ZY Yi, KX Zhang, T Chen… - Surface Science Reports, 2021 - Elsevier
The formation of chiral nanostructures via molecular assembly and reaction on solid
surfaces is a ubiquitous surface process due to the symmetry-breaking at 2D surface …

Chirality-dependent electron spin filtering by molecular monolayers of helicenes

M Kettner, VV Maslyuk, D Nürenberg… - The journal of …, 2018 - ACS Publications
The interaction of low-energy photoelectrons with well-ordered monolayers of enantiopure
helical heptahelicene molecules adsorbed on metal surfaces leads to a preferential …

Metal ion and guest-mediated spontaneous resolution and solvent-induced chiral Symmetry breaking in guanine-based metallosupramolecular networks

A Cucinotta, C Kahlfuss, A Minoia, S Eyley… - Journal of the …, 2022 - ACS Publications
Two-dimensional (2D) chirality has been actively studied in view of numerous applications
of chiral surfaces such as in chiral resolutions and enantioselective catalysis. Here, we …

Enantiomer surface chemistry: conglomerate versus racemate formation on surfaces

S Dutta, AJ Gellman - Chemical Society Reviews, 2017 - pubs.rsc.org
Research on surface chirality is motivated by the need to develop functional chiral surfaces
for enantiospecific applications. While molecular chirality in 3D has been the subject of study …

Stereochemical recognition of helicenes on metal surfaces

KH Ernst - Accounts of chemical research, 2016 - ACS Publications
Conspectus The chiral recognition among biomolecules is fundamentally important for many
processes of life, including the stereochemistry of evolution. Of special interest is chiral …

Two-Dimensional Crystal Transition from Radialene to Cumulene on Ag (111) via Retro-[2+ 1] Cycloaddition

JW Liu, Y Wang, LX Kang, Y Zhao… - Journal of the …, 2023 - ACS Publications
Two-dimensional (2D) crystal-to-crystal transition is an important method in crystal
engineering because of its ability to directly create diverse crystal materials from one crystal …

Organocatalytic asymmetric Biginelli-like reaction involving isatin

M Stucchi, G Lesma, F Meneghetti… - The Journal of …, 2016 - ACS Publications
The first asymmetric, Brønsted acid catalyzed Biginelli-like reaction of a ketone has been
developed, employing N-substituted isatins as carbonyl substrates, and urea and alkyl …

Deposition of chiral heptahelicene molecules on ferromagnetic Co and Fe thin-film substrates

MR Safari, F Matthes, KH Ernst, DE Bürgler… - Nanomaterials, 2022 - mdpi.com
The discovery of chirality-induced spin selectivity (CISS), resulting from an interaction
between the electron spin and handedness of chiral molecules, has sparked interest in …

Chiral Amplification through the Interplay of Racemizing Conditions and Asymmetric Crystal Growth

SW van Dongen, I Ahlal, M Leeman… - Journal of the …, 2022 - ACS Publications
Amplification of enantiomeric excesses (ee) is routinely observed during chiral crystallization
of conglomerate crystals for which the enantiomers undergo racemization in solution …