[HTML][HTML] Rare-earth based tetrapyrrolic sandwiches: chemistry, materials and applications

AG Martynov, Y Horii, K Katoh, Y Bian, J Jiang… - Chemical Society …, 2022 - pubs.rsc.org
The unique properties of natural tetrapyrrolic compounds have inspired the rapid growth of
research interest in the design and synthesis of artificial porphyrinoids and their metal …

Functional molecular switches involving tetrapyrrolic macrocycles

AG Martynov, EA Safonova, AY Tsivadze… - Coordination Chemistry …, 2019 - Elsevier
Porphyrins and phthalocyanines are well-known colourful compounds, which attract much
attention in various fields of science and technology, including the area of molecular …

NMR thermosensing properties on binuclear triple-decker complexes of terbium (III) and dysprosium (III) with 15-crown-5-phthalocyanine

SP Babailov, MA Polovkova, GA Kirakosyan… - Sensors and Actuators A …, 2021 - Elsevier
In this paper, we have firstly demonstrated the thermosensing properties of binuclear triple-
decker terbium (III) and dysprosium (III) complexes with 15-crown-5-phthalocyanine Tb 2 …

A molecular chameleon: reversible pH-and cation-induced control of the optical properties of phthalocyanine-based complexes in the visible and near-infrared …

EA Safonova, AG Martynov, SE Nefedov… - Inorganic …, 2016 - ACS Publications
A series of novel nonperipherally substituted tetra-15-crown-5-dibutoxyoxanthrenocyanines
(H2, Mg, Zn), acting as chameleons with the unique properties of switchable absorption and …

Cation-induced dimerization of heteroleptic crown-substituted trisphthalocyaninates as revealed by X-ray diffraction and NMR spectroscopy

AG Martynov, MA Polovkova, GS Berezhnoy… - Inorganic …, 2020 - ACS Publications
We report comprehensive X-ray diffraction and NMR studies of potassium-induced
dimerization of heteroleptic triple-decker crown-phthalocyaninates [(15C5) 4Pc] M (Pc) M …

Unexpected Supramolecular-Induced Redox Switching in Sandwich Gd Bisphthalocyaninate

AA Sinelshchikova, LA Lapkina, VE Larchenko… - Inorganic …, 2024 - ACS Publications
The redox state of the phthalocyanine in sandwich lanthanide complexes is crucial for their
applications. In this work, we demonstrate that the cation-induced supramolecular assembly …

Heteroleptic Crown-Substituted Tris (phthalocyaninates) as Dynamic Supramolecular Scaffolds with Switchable Rotational States and Tunable Magnetic Properties

AG Martynov, MA Polovkova, GS Berezhnoy… - Inorganic …, 2021 - ACS Publications
Herein we report single-crystal X-ray diffraction characterization and complementary
solution studies of supramolecular interaction between potassium salts and heteroleptic …

Determination of the structural parameters of heteronuclear (phthalocyaninato) bis (crownphthalocyaninato) lanthanide (III) triple-deckers in solution by simultaneous …

MA Polovkova, AG Martynov, KP Birin… - Inorganic …, 2016 - ACS Publications
Application of a general and convenient approach to the synthesis of heteronuclear crown-
substituted triple-decker phthalocyaninates afforded two series of complexes containing one …

Orientation-induced redox isomerism in planar supramolecular systems

SL Selektor, AV Shokurov, VV Arslanov… - The Journal of …, 2014 - ACS Publications
In this work, a previously undescribed phenomenon of orientation-induced redox isomerism
in a Langmuir monolayer is revealed in the case of cerium bis-[tetra-(15-crown-5) …

The crucial role of self-assembly in nonlinear optical properties of polymeric composites based on crown-substituted ruthenium phthalocyaninate

YG Gorbunova, AD Grishina, AG Martynov… - Journal of Materials …, 2015 - pubs.rsc.org
Ruthenium (II) tetra-15-crown-5-phthalocyaninate with axially coordinated molecules of
pyrazine [(15C5) 4Pc] Ru (pyz) 2 (1) was synthesized from a carbonyl complex [(15C5) 4Pc] …