Recent advances in the development of phenothiazine and its fluorescent derivatives for optoelectronic applications

F Khan, R Misra - Journal of Materials Chemistry C, 2023 - pubs.rsc.org
Phenothiazine is one of the most extensively investigated aromatic compounds owing to its
unique optical and electronic properties, low cost, and easy functionalization. In recent …

Detection of the Dark States in Thermally Activated Delayed Fluorescence (TADF) Process of Electron Donor‐Acceptor Dyads: Insights from Optical Transient …

X Zhang, X Zhao, K Ye, J Zhao - Chemistry–A European …, 2023 - Wiley Online Library
The photophysical processes involved in the electron donor‐acceptor thermally activated
delayed fluorescence (TADF) emitters are complicated and controversial. The recent …

Heavy atom‐free, mitochondria‐targeted, and activatable photosensitizers for photodynamic therapy with real‐time in‐situ therapeutic monitoring

J Miao, Y Huo, G Yao, Y Feng, J Weng… - Angewandte Chemie …, 2022 - Wiley Online Library
Based on spin‐orbit charge transfer intersystem crossing mechanism, two heavy‐atom‐free
photosensitizers (PSs) BDP1/BDP2 with absorption maxima at 506 nm/660 nm were …

Tuning the fluorescence and the intramolecular charge transfer of phenothiazine dipolar and quadrupolar derivatives by oxygen functionalization

Y Rout, C Montanari, E Pasciucco… - Journal of the …, 2021 - ACS Publications
A series of new naphthalimide and phenothiazine-based push–pull systems (NPI-PTZ1–5),
in which we structurally modulate the oxidation state of the sulfur atom in the thiazine ring, ie …

Multiphoton excited singlet/triplet mixed self-trapped exciton emission

R Zhou, L Sui, X Liu, K Liu, D Guo, W Zhao… - Nature …, 2023 - nature.com
Multiphoton excited luminescence is of paramount importance in the field of optical detection
and biological photonics. Self-trapped exciton (STE) emission with self-absorption-free …

Electron spin resonance resolves intermediate triplet states in delayed fluorescence

BH Drummond, N Aizawa, Y Zhang, WK Myers… - Nature …, 2021 - nature.com
Molecular organic fluorophores are currently used in organic light-emitting diodes, though
non-emissive triplet excitons generated in devices incorporating conventional fluorophores …

Long‐Lived Charge‐Transfer State Induced by Spin‐Orbit Charge Transfer Intersystem Crossing (SOCT‐ISC) in a Compact Spiro Electron Donor/Acceptor Dyad

D Liu, AM El‐Zohry, M Taddei, C Matt… - Angewandte …, 2020 - Wiley Online Library
We prepared conceptually novel, fully rigid, spiro compact electron donor (Rhodamine B,
lactam form, RB)/acceptor (naphthalimide; NI) orthogonal dyad to attain the long‐lived triplet …

Long-Lived Charge-Separated State in Naphthalimide–Phenothiazine Compact Electron Donor–Acceptor Dyads: Effect of Molecular Conformation Restriction and …

X Xiao, Y Yan, AA Sukhanov, S Doria… - The Journal of …, 2023 - ACS Publications
To study the charge separation (CS) and long-lived CS state, we prepared a series of dyads
based on naphthalimide (NI, electron acceptor) and phenothiazine (PTZ, electron donor) …

Heavy atom-free triplet photosensitizer based on thermally activated delayed fluorescence material for NIR-to-blue triplet-triplet annihilation upconversion

H Liang, X Liu, L Tang, Z Mahmood, Z Chen… - Chinese Chemical …, 2023 - Elsevier
Triplet-triplet annihilation (TTA) upconversion-based materials have potential application in
the broad range of research areas, including photocatalysis and life sciences. However …

Long-lived charge separated state and thermally activated delayed fluorescence in anthraquinone-phenoxazine electron donor–acceptor dyads

X Zhao, J Zhao - Chemical Communications, 2022 - pubs.rsc.org
Long-lived charge separated (CS) triplet state (2.6 μs) and thermally activated delayed
fluorescence (TADF)[τ= 282 ns (90.4%)/2.4 μs (9.6%)] were observed in an anthraquinone …