The halogen-atom transfer (XAT) is one of the most important and applied processes for the
generation of carbon radicals in synthetic chemistry. In this review, we summarize and …

This review is an update on tris (trimethylsilyl) silane, TTMSS, in organic chemistry, focusing
on the advancements of the past decade. The overview includes a wide range of chemical …

This review summarizes the recent progress the emerging area of photochemical reaction
initiated by Electron-donor-acceptor (EDA) complex in synthetic organic chemistry. Recent …

We recently reported a new method for the direct dehydrogenative C–H silylation of
heteroaromatics utilizing Earth-abundant potassium tert-butoxide. Herein we report a …

Vinylsilanes are versatile synthetic building blocks, which in recent years have played an
increasing role in the synthesis of complex molecules. This article provides an overview of …

Polysilalkylene siloxanes or 'hybrid silicones' are a comparatively new class of polymeric
materials combining the chemical properties of silicones and paraffins in a unique way. They …

Tetrabutylammonium decatungstate has been used for the photocatalytic activation of the
Si− H bond in trisubstituted silanes and applied for the hydrosilylation of electron‐poor …

Intramolecular homolytic aromatic silylation of biphenyl-2-hydrosilanes via silyl radicals has
been developed for the synthesis of silafluorenes. Moreover, silaindenes are synthesized …

Hydrodesulfurization (HDS) is the process by which sulfur-containing impurities are
removed from petroleum streams, typically using a heterogeneous, sulfided transition metal …

A combined tris (trimethylsilyl) silane and visible-light-promoted intramolecular reductive
cyclization protocol for the synthesis of indoles and oxindoles has been developed. This …