This chapter reviews the reaction chemistry of uranium complexes with small molecules of
industrial and biological importance. Specifically, carbon monoxide (CO), nitrogen monoxide …

Using two transition metals to simultaneously catalyze a reaction can offer distinct
opportunities for reactivity and selectivity when compared to using single-metal catalyst …

Abstract Uranium nitride [U≡ N] x is an alternative nuclear fuel that has great potential in the
expanding future of nuclear power; however, very little is known about the U≡ N …

This Perspective provides a detailed overview of the chemistry of low-valent (di-and
trivalent) uranium. The reactivity of uranium (II) and uranium (III) complexes is discussed …

A series of uranium (VI)–acetylide complexes of the general formula UVI (O)(C≡ C–C6H4–
R)[N (SiMe3) 2] 3, with variation of the para substituent (R= NMe2, OMe, Me, Ph, H, Cl) on …

Thermally stable uranium (VI)–methyl and− acetylide complexes: UVIOR [N (SiMe3) 2] 3
R=− CH3,− C CPh were prepared in which coordination of the hydrocarbyl group is …

Résumé A series of uranium (IV) mixed-ligand amide–halide/pseudohalide complexes (C 5
Me 5) 2 U [N (SiMe 3) 2](X)(X= F (1), Cl (2), Br (3), I (4), N 3 (5), NCO (6)),(C 5 Me 5) 2 U …

Addition of potassium graphite (KC8) to a solution of (η5-C5Me5) 2UCl2 (1) and 2, 2′-
bipyridine (bipy) gives the uranium bipyridyl metallocene (η5-C5Me5) 2U (bipy)(2) in good …

A family of uranium (III) complexes of the form Tp* 2UX (Tp*= hydrotris (3, 5-
dimethylpyrazolyl) borate, X= CCPh (2-CCPh), CCSiMe3 (3-CCSiMe 3), NHPh (4-NHPh) …

A new monoiodide U (III) complex anchored on a hexadentate dianionic 1, 4, 8, 11-
tetraazacyclotetradecane-based bis (phenolate) ligand,[U (κ6-{(tBu2ArO) 2Me2-cyclam}) …