Rational design of photocatalysts for controlled polymerization: effect of structures on photocatalytic activities
Over the past decade, the use of photocatalysts (PCs) in controlled polymerization has
brought new opportunities in sophisticated macromolecular synthesis. However, the …
brought new opportunities in sophisticated macromolecular synthesis. However, the …
Reversible-deactivation radical polymerization (Controlled/living radical polymerization): From discovery to materials design and applications
Reversible-deactivation radical polymerization (RDRP) processes, such as atom transfer
radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT) …
radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT) …
Up in the air: oxygen tolerance in controlled/living radical polymerisation
The requirement for deoxygenation in controlled/living radical polymerisation (CLRP) places
significant limitations on its widespread implementation by necessitating the use of large …
significant limitations on its widespread implementation by necessitating the use of large …
Fluoropolymer nanoparticles synthesized via reversible-deactivation radical polymerizations and their applications
Z Zhang, K Chen, B Ameduri, M Chen - Chemical Reviews, 2023 - ACS Publications
Fluorinated polymeric nanoparticles (FPNPs) combine unique properties of fluorocarbon
and polymeric nanoparticles, which has stimulated massive interest for decades. However …
and polymeric nanoparticles, which has stimulated massive interest for decades. However …
Rapid high‐resolution 3D printing and surface functionalization via type I photoinitiated RAFT polymerization
RAFT facilitated digital light projection 3D printing of polymeric materials provides a
convenient and facile route for inducing post‐fabrication transformations via reactivation of …
convenient and facile route for inducing post‐fabrication transformations via reactivation of …
Controlled Radical Copolymerization toward Well‐Defined Fluoropolymers
K Chen, X Guo, M Chen - Angewandte Chemie, 2023 - Wiley Online Library
In the past 80 years, fluoropolymers have found broad applications in both industrial and
academic settings, owing to their unique physicochemical properties. Copolymerizations of …
academic settings, owing to their unique physicochemical properties. Copolymerizations of …
Evolution and future directions of metal-free atom transfer radical polymerization
The increasing impact of atom transfer radical polymerization (ATRP) in fields beyond
traditional polymer science has necessitated the development of alternative strategies for …
traditional polymer science has necessitated the development of alternative strategies for …
Polymerization in living organisms
Vital biomacromolecules, such as RNA, DNA, polysaccharides and proteins, are
synthesized inside cells via the polymerization of small biomolecules to support and multiply …
synthesized inside cells via the polymerization of small biomolecules to support and multiply …
Controlled radical copolymerization of fluoroalkenes by using light-driven redox-relay catalysis
Y Zhao, Y Chen, H Zhou, Y Zhou, K Chen, Y Gu… - Nature …, 2023 - nature.com
Fluoroalkenes are feedstocks in the manufacture of high-performance fluoropolymers with
various applications. However, the synthesis of well-defined fluoropolymers typically …
various applications. However, the synthesis of well-defined fluoropolymers typically …
The emergence of reversible–deactivation radical polymerization in 3D printing
The majority of materials 3D printed using vat photopolymerization techniques are prepared
by uncontrolled polymerization methods and cannot be easily modified to introduce …
by uncontrolled polymerization methods and cannot be easily modified to introduce …