Nonequilibrium processes in polymer membrane formation: Theory and experiment

M Müller, V Abetz - Chemical reviews, 2021 - ACS Publications
Porous polymer and copolymer membranes are useful for ultrafiltration of functional
macromolecules, colloids, and water purification. In particular, block copolymer membranes …

GISAXS and GISANS as metrology technique for understanding the 3D morphology of block copolymer thin films

P Müller-Buschbaum - European Polymer Journal, 2016 - Elsevier
Grazing incidence small angle X-ray scattering (GISAXS) and grazing incidence small angle
neutron scattering (GISANS) have developed as advanced thin film characterization …

Restructuring in block copolymer thin films: In situ GISAXS investigations during solvent vapor annealing

D Posselt, J Zhang, DM Smilgies, AV Berezkin… - Progress in polymer …, 2017 - Elsevier
Block copolymer (BCP) thin films have been proposed for a number of nanotechnology
applications, such as nanolithography and as nanotemplates, nanoporous membranes and …

A polymer microgel at a liquid–liquid interface: theory vs. computer simulations

AM Rumyantsev, RA Gumerov, II Potemkin - Soft Matter, 2016 - pubs.rsc.org
We propose a mean-field theory and dissipative particle dynamics (DPD) simulations of
swelling and collapse of a polymer microgel adsorbed at the interface of two immiscible …

Vertical domain orientation in cylinder-forming diblock copolymer films upon solvent vapor annealing

AV Berezkin, CM Papadakis, II Potemkin - Macromolecules, 2016 - ACS Publications
Dissipative particle dynamics was applied to simulate solvent vapor annealing in films of
cylinder-forming diblock copolymers. Our simulations reveal a wide range of conditions …

Mixing of two immiscible liquids within the polymer microgel adsorbed at their interface

RA Gumerov, AM Rumyantsev, AA Rudov… - ACS Macro …, 2016 - ACS Publications
We report on the behavior of two immiscible liquids within polymer microgel adsorbed at
their interface. By means of dissipative particle dynamics (DPD) simulations and theoretical …

Temperature-controlled solvent vapor annealing of thin block copolymer films

X Cheng, A Böker, L Tsarkova - Polymers, 2019 - mdpi.com
Solvent vapor annealing is as an effective and versatile alternative to thermal annealing to
equilibrate and control the assembly of polymer chains in thin films. Here, we present …

Amphiphilic arborescent copolymers and microgels: from unimolecular micelles in a selective solvent to the stable monolayers of variable density and nanostructure at …

RA Gumerov, AA Rudov, W Richtering… - … applied materials & …, 2017 - ACS Publications
Amphiphilic arborescent block copolymers of two generations (G2 and G3) and polymer
microgels, obtained via cross-linking of diblock copolymers, were studied in a selective …

Self-assembly of gradient copolymers in a selective solvent. New structures and comparison with diblock and statistical copolymers

VS Kravchenko, V Abetz, II Potemkin - Polymer, 2021 - Elsevier
We perform comparative studies of self-assembly of equivalent statistical, diblock and
gradient AB copolymers in a selective solvent using dissipative particle dynamics …

How much do ultrathin polymers with intrinsic microporosity swell in liquids?

W Ogieglo, B Ghanem, X Ma, I Pinnau… - The Journal of …, 2016 - ACS Publications
As synthetic membrane materials, polymers with intrinsic microporosity (PIMs) have
demonstrated unprecedented permeation and molecular-separation properties. Here, we …