Diterpenoids

JR Hanson - Natural product reports, 2004 - pubs.rsc.org
Covering 2002. Previous review: Nat. Prod. Rep., 2003, 20, 70 This review covers the
isolation and structures of diterpenoids including labdanes, clerodanes, abietanes …

Development of New Gold (I)‐Catalyzed Carbocyclizations and their Applications in the Synthesis of Natural Products

P McGee, J Brousseau, L Barriault - Israel Journal of Chemistry, 2018 - Wiley Online Library
For many years, gold was considered inactive to catalyze organic transformations. In the last
two decades, gold (I/III) complexes have emerged as efficient catalyst for the formation of C …

Iodine, a mild reagent for the aromatization of terpenoids

V Domingo, C Prieto, L Silva, JML Rodilla… - Journal of Natural …, 2016 - ACS Publications
Efficient procedures based on the use of iodine for the aromatization of a series of
terpenoids possessing diene and homoallylic or allylic alcohol functionalities are described …

Review of the Total Synthesis of the Aromatic Abietane Diterpenoid Ferruginol

M Li, P Chen, H Liu, J Huang, Y Chen - Synthesis, 2024 - thieme-connect.com
The biological properties and synthesis of ferruginol as a classical abietane-type diterpenoid
with an aromatic C ring are reviewed. A strategy overview from 1954 to 2023 toward the total …

Scalable synthesis of methyl ent-isocopalate and its derivatives

SK Hua, J Wang, XB Chen, ZY Xu, BB Zeng - Tetrahedron, 2011 - Elsevier
An efficient and convenient synthetic route was developed to prepare the tricycle diterpene
intermediates 1–3 starting from commercially available (−)-sclareol. This improved approach …

Ti (III)-catalyzed cyclizations of ketoepoxypolyprenes: control over the number of rings and unexpected stereoselectivities

SP Morcillo, D Miguel, S Resa… - Journal of the …, 2014 - ACS Publications
We describe a new strategy to control the number of cyclization steps in bioinspired radical
(poly) cyclizations involving epoxypolyenes containing keto units positioned along the …

Iodine‐Promoted Metal‐Free Aromatization: Synthesis of Biaryls, Oligo p‐Phenylenes and A‐Ring Modified Steroids

V Domingo, C Prieto, A Castillo, L Silva… - Advanced Synthesis …, 2015 - Wiley Online Library
We describe efficient procedures based on the use of iodine for the synthesis of biaryls from
arylcyclohexenols or arylcyclohexanols using sub‐stoichiometric/catalytic iodine and …

Total synthesis of isofregenedadiol

SE Kurhade, AI Sanchawala, V Ravikumar… - Organic …, 2011 - ACS Publications
The first total synthesis of isofregenedadiol, a bicyclic diterpene isolated from H. Viscosum,
is reported starting from a d-(−)-pantolactone chiral pool. A one-pot quadruple reaction …

Synthesis of 12-epi-ent-polyalthenol an antitumour indole sesquiterpene alkaloid

IS Marcos, RF Moro, I Costales, P Basabe, D Díez… - Tetrahedron, 2012 - Elsevier
The synthesis of 12-epi-ent-polyalthenol, 10, and its epimer at C-19, 11, from ent-halimic
acid as starting material has been carried out. The structure of the natural product …

Short and efficient synthesis of (+)-subersic acids

P Basabe, A Diego, S Delgado, D Dıez, IS Marcos… - Tetrahedron, 2003 - Elsevier
Short and efficient synthesis of (+)-subersic acids - ScienceDirect Skip to main contentSkip to
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