Enantiomers, where chirality arises from restricted rotation around a single bond, are
atropisomers. Due to the unique nature of the origins of their chirality, synthetic strategies to …

Chiral organosulfur compounds are not only widely distributed in bioactive natural products
and pharmaceuticals, but also play a significant role in chiral ligands/catalysts. Throughout …

We present herein an unprecedented stereoselective synthesis of triaryl-2-pyrones with
monoaxial or contiguous diaxes from readily available starting materials. This N-heterocyclic …

We herein introduce biarylhemiboronic esters as a new type of bridged biaryl reagent for
asymmetric synthesis of axially chiral biaryl structures, and the palladium-catalyzed …

The development of catalytic asymmetric reaction with water as the reactant is challenging
due to the reactivity‐and stereoselectivity‐control issues resulted from the low nucleophilicity …

We describe herein an intriguing method for the synthesis of biaryl aldehydes bearing both
axial and central chirality through a desymmetric [3+ 2] cycloaddition reaction of activated …

The development of efficient processes for the preparation of structurally diverse axially
chiral biaryls has been an important goal in synthetic organic chemistry and asymmetric …

A modular and practical click chemistry for atroposelective synthesis of 1-triazolyl-2-
naphthylamines is developed. In this protocol, a variety of aromatic or aliphatic azides, and 1 …

Axially chiral architectures exist widely in natural products, biologically relevant molecules,
chiral ligands and catalysts as well as functional materials. Therefore, catalytic asymmetric …

Atropisomeric compounds—stereoisomers that arise from the restricted rotation about a
single bond—have attracted widespread attention in recent years due to their immense …