Donor-acceptor cyclopropanes are known as a versatile carbon-based building block in
organic synthesis. Due to their unique characteristics, 2-substituted dA cyclopropanes easily …

The chemistry of cyclic sulfinic acid derivatives (sultines and cyclic sulfinamides) was
underdeveloped for a long time due to their inaccessibility. Considering the importance of …

sulfinamides, sulfonamides, and sulfonimidamides are in-demand motifs in medicinal
chemistry, yet methods for the synthesis of alkyl variants that start from simple, readily …

A novel class of highly activated donor‐acceptor cyclopropanes bearing only a single,
vinylogous acceptor is presented. These strained moieties readily undergo cycloadditions …

Abstract A novel enantioselective (8+ 3) cycloaddition between donor–acceptor
cyclopropanes and heptafulvenoids catalysed by a chiral bifunctional Brønsted base is …

The evolving use of covalent ligands as chemical probes and therapeutic agents could
greatly benefit from an expanded array of cysteine-reactive electrophiles for efficient and …

The use of benzotriazoles as nucleophilic triggers in the three-component Yb (OTf) 3-
catalyzed ring-opening 1, 3-aminofunctionalization of donor–acceptor (D–A) cyclopropanes …

A new N-silyl sulfinylamine reagent allows the rapid preparation of a broad range of (hetero)
aryl, alkenyl, and alkyl primary sulfinamides, using Grignard, organolithium, or organozinc …

Two-step, ring-opening 1, 3-carbothiolation of donor–acceptor (D–A) cyclopropanes
employing alkyl halides and in situ generated dithiocarbamates (from amines and CS2) has …

A facile and efficient route to dithiolanes starting from donor–acceptor cyclopropanes is
reported. Potassium p-toluenethiosulfonate has been established as the reagent of choice …