Oxygen defects and surface chemistry of ceria: quantum chemical studies compared to experiment

J Paier, C Penschke, J Sauer - Chemical reviews, 2013 - ACS Publications
As one of the most significant rare earth oxides, ceria (CeO 2) has attracted much interest
over the past decades. In catalysis, 1, 2 CeO2 serves as a widely used support material and …

CeO2-based oxygen storage capacity materials in environmental and energy catalysis for carbon neutrality: extended application and key catalytic properties

SY Ahn, WJ Jang, JO Shim, BH Jeon, HS Roh - Catalysis Reviews, 2024 - Taylor & Francis
Reducing carbon dioxide emissions is one of the largest energy and environmental
challenges currently faced globally. To achieve carbon neutrality, the development of new …

Structure of the catalytically active copper–ceria interfacial perimeter

A Chen, X Yu, Y Zhou, S Miao, Y Li, S Kuld… - Nature Catalysis, 2019 - nature.com
Cu/CeO2 catalysts are highly active for the low-temperature water–gas shift—a core reaction
in syngas chemistry for tuning the H2/CO/CO2 proportions in feed streams—but the direct …

Pt atomic single-layer catalyst embedded in defect-enriched ceria for efficient CO oxidation

S Xie, L Liu, Y Lu, C Wang, S Cao, W Diao… - Journal of the …, 2022 - ACS Publications
The local coordination structure of metal sites essentially determines the performance of
supported metal catalysts. Using a surface defect enrichment strategy, we successfully …

Photosensitized peroxidase mimicry at the hierarchical 0D/2D heterojunction‐like quasi metal‐organic framework interface for boosting biocatalytic disinfection

L Huang, DW Sun, H Pu - Small, 2022 - Wiley Online Library
Metal‐organic frameworks (MOFs) are a versatile toolbox for the bioinspired design of
nanozymes for antibacterial applications and beyond, however, designing a nanozyme by …

Insight into the effect of morphology on catalytic performance of porous CeO2 nanocrystals for H2S selective oxidation

X Zheng, Y Li, L Zhang, L Shen, Y Xiao, Y Zhang… - Applied Catalysis B …, 2019 - Elsevier
Shape-specific CeO 2 nanocrystals (rods, cubes, spheres and nanoparticles) with well-
defined crystal facets and hierarchically porous structure were successfully synthesized and …

Creating single-atom Pt-ceria catalysts by surface step decoration

F Dvořák, M Farnesi Camellone, A Tovt… - Nature …, 2016 - nature.com
Single-atom catalysts maximize the utilization of supported precious metals by exposing
every single metal atom to reactants. To avoid sintering and deactivation at realistic reaction …

High Catalytic Activity and Chemoselectivity of Sub-nanometric Pd Clusters on Porous Nanorods of CeO2 for Hydrogenation of Nitroarenes

S Zhang, CR Chang, ZQ Huang, J Li, Z Wu… - Journal of the …, 2016 - ACS Publications
Sub-nanometric Pd clusters on porous nanorods of CeO2 (PN-CeO2) with a high Pd
dispersion of 73.6% exhibit the highest catalytic activity and best chemoselectivity for …

Design of effective catalysts for selective alkyne hydrogenation by doping of ceria with a single-atom promotor

C Riley, S Zhou, D Kunwar, A De La Riva… - Journal of the …, 2018 - ACS Publications
Since the discovery that ceria is an active catalyst for selective hydrogenation of alkynes,
there has been much debate on the catalytic mechanism. In this work, we propose, based on …

Nanostructured ceria-based materials: synthesis, properties, and applications

C Sun, H Li, L Chen - Energy & Environmental Science, 2012 - pubs.rsc.org
The controllable synthesis of nanostructured CeO2-based materials is an imperative issue
for environment-and energy-related applications. In this review, we present the recent …