Anion–π catalysis enabled by the mechanical bond

JRJ Maynard, B Galmés, AD Stergiou… - Angewandte Chemie …, 2022 - Wiley Online Library
We report a series of rotaxane‐based anion–π catalysts in which the mechanical bond
between a bipyridine macrocycle and an axle containing an NDI unit is intrinsic to the activity …

Inhibition of Thiol‐Mediated Uptake with Irreversible Covalent Inhibitors

B Lim, Y Cheng, T Kato, AT Pham, E Le Du… - Helvetica Chimica …, 2021 - Wiley Online Library
Thiol‐mediated uptake is emerging as method of choice to penetrate cells. This study
focuses on irreversible covalent inhibitors of thiol‐mediated uptake. High‐content high …

An Orthogonal Dynamic Covalent Chemistry Tool for Ring‐Opening Polymerization of Cyclic Oligochalcogenides on Detachable Helical Peptide Templates

Q Laurent, N Sakai, S Matile - Chemistry–A European Journal, 2022 - Wiley Online Library
A model system is introduced as a general tool to elaborate on orthogonal templation of
dynamic covalent ring‐opening polymerization (ODC‐TROP). The tool consists of 310 …

Stabilizing role of water solvation on anion− π interactions in proteins

K Balamurugan, MT Pisabarro - ACS omega, 2021 - ACS Publications
In this work, anion− π interactions between sulfate groups (SO42–) and protein aromatic
amino acids (AAs)(histidine protonated (HisP), histidine neutral (HisN), tyrosine (Tyr) …

Anion-π Catalysis: A novel supramolecular approach for chemical and biological transformations

IA Rather, R Ali - Chirality, 2021 - books.google.com
Catalysts by virtue of lowering the activation barrier helps in the completion of a chemical
reaction in a lesser amount of time without being themselves consumed. Utilizing the diverse …

Investigation of positively charged supramolecular cages towards guest-uptake and catalysis

M Zenka - 2023 - edoc.unibas.ch
Over the recent decades, interest in anion-$\pi $ interactions has grown rapidly.
Naphthalene diimide (NDI) compounds were found to offer a useful $\pi $-acidic platform …

New Trends and Supramolecular Approaches in Anion‐Binding Catalysis

MC Pérez‐Aguilar, M Gómez‐Martínez… - Anion‐Binding …, 2022 - Wiley Online Library
This chapter aims at giving an overview of some emerging directions that are still
underrepresented within the existing portfolio of anion‐binding catalysis. In this regard …

11.3 Combination of Metal and Anion-Binding Catalysis

A Ir-complex - Anion-Binding Catalysis, 2022 - Wiley Online Library
Besides the above-described photoredox cocatalyzed processes involving metal species,
the idea of combining anion binding and metal catalysis is largely appealing as it might offer …

Mechanochemical synthesis of diimide based electron acceptors for organic photovoltaics applications

H Emerit - 2022 - sussex.figshare.com
It has been predicted that solar energy will play a key role in solving the serious
environmental problems that face our planet. The pursuit of clean, renewable, cost-effective …

[PDF][PDF] Anion-π Catalysis with Peptides and Synthesis of Thiol-Mediated Uptake Inhibitors

AT PHAM - access.archive-ouverte.unige.ch
Despite being the youngest in the noncovalent interaction family, anion-π interaction has
found its applications in the last decade. From the early applications in anion recognition …