Molecular catalysts with diphosphine ligands containing pendant amines
Pendant amines play an invaluable role in chemical reactivity, especially for molecular
catalysts based on earth-abundant metals. As inspired by [FeFe]-hydrogenases, which …
catalysts based on earth-abundant metals. As inspired by [FeFe]-hydrogenases, which …
Artificial photosynthesis: opportunities and challenges of molecular catalysts
Molecular catalysis plays an essential role in both natural and artificial photosynthesis (AP).
However, the field of molecular catalysis for AP has gradually declined in recent years …
However, the field of molecular catalysis for AP has gradually declined in recent years …
Introducing Water‐Network‐Assisted Proton Transfer for Boosted Electrocatalytic Hydrogen Evolution with Cobalt Corrole
X Li, B Lv, XP Zhang, X Jin, K Guo… - Angewandte Chemie …, 2022 - Wiley Online Library
Proton transfer is vital for many biological and chemical reactions. Hydrogen‐bonded water‐
containing networks are often found in enzymes to assist proton transfer, but similar strategy …
containing networks are often found in enzymes to assist proton transfer, but similar strategy …
Nitrogen atom insertion into indenes to access isoquinolines
We report a convenient protocol for a nitrogen atom insertion into indenes to afford
isoquinolines. The reaction uses a combination of commercially available phenyliodine (III) …
isoquinolines. The reaction uses a combination of commercially available phenyliodine (III) …
Enhanced photoactivity and oxidizing ability simultaneously via internal electric field and valence band position by crystal structure of bismuth oxyiodide
Y Guo, W Shi, Y Zhu, Y Xu, F Cui - Applied Catalysis B: Environmental, 2020 - Elsevier
Herein, the photoactivity and oxidizing ability of bismuth oxyiodide were enhanced
simultaneously via crystal structure regulation. The internal electric field is enhanced via unit …
simultaneously via crystal structure regulation. The internal electric field is enhanced via unit …
Electrocatalytic hydrogen evolution with a cobalt complex bearing pendant proton relays: acid strength and applied potential govern mechanism and stability
N Queyriaux, D Sun, J Fize, J Pécaut… - Journal of the …, 2019 - ACS Publications
[Co (bapbpy) Cl]+(bapbpy: 6, 6′-bis (2-aminopyridyl)-2, 2′-bipyridine) is a polypyridyl
cobalt (II) complex bearing both a redox-active bipyridine ligand and pendant proton relays …
cobalt (II) complex bearing both a redox-active bipyridine ligand and pendant proton relays …
Switching Electrocatalytic Hydrogen Evolution Pathways through Electronic Tuning of Copper Porphyrins
X Peng, M Zhang, H Qin, J Han, Y Xu… - Angewandte Chemie …, 2024 - Wiley Online Library
The electronic structure of metal complexes plays key roles in determining their catalytic
features. However, controlling electronic structures to regulate reaction mechanisms is of …
features. However, controlling electronic structures to regulate reaction mechanisms is of …
Hydrogen evolution with hot electrons on a plasmonic-molecular catalyst hybrid system
A Dey, A Mendalz, A Wach, RB Vadell… - Nature …, 2024 - nature.com
Plasmonic systems convert light into electrical charges and heat, mediating catalytic
transformations. However, there is ongoing controversy regarding the involvement of hot …
transformations. However, there is ongoing controversy regarding the involvement of hot …
Comparing electrocatalytic hydrogen and oxygen evolution activities of first-row transition metal complexes with similar coordination environments
X Jin, X Li, H Lei, K Guo, B Lv, H Guo, D Chen… - Journal of Energy …, 2021 - Elsevier
Developing cheap and efficient electrocatalysts for water splitting is required for energy
conversion techniques. Many first-row transition metal complexes have been shown to be …
conversion techniques. Many first-row transition metal complexes have been shown to be …
Homolytic versus heterolytic hydrogen evolution reaction steered by a steric effect
X Guo, N Wang, X Li, Z Zhang, J Zhao… - Angewandte Chemie …, 2020 - Wiley Online Library
Several H− H bond forming pathways have been proposed for the hydrogen evolution
reaction (HER). Revealing these HER mechanisms is of fundamental importance for the …
reaction (HER). Revealing these HER mechanisms is of fundamental importance for the …