Imaging the dynamics of gas phase reactions

MNR Ashfold, NH Nahler, AJ Orr-Ewing… - Physical Chemistry …, 2006 - pubs.rsc.org
Ion imaging methods are making ever greater impact on studies of gas phase molecular
reaction dynamics. This article traces the evolution of the technique, highlights some of the …

Vibrational control of bimolecular reactions with methane by mode, bond, and stereo selectivity

K Liu - Annual review of physical chemistry, 2016 - annualreviews.org
Vibrational motions of a polyatomic molecule are multifold and can be as simple as stretches
or bends or as complex as concerted motions of many atoms. Different modes of excitation …

Quasiclassical trajectory calculations of correlated product distributions for the F+ CHD3 (v1=, 1) reactions using an ab initio potential energy surface

G Czakó, JM Bowman - The Journal of chemical physics, 2009 - pubs.aip.org
We report quasiclassical trajectory (QCT) calculations of the correlated product distributions
and branching ratios of the reactions F+ CHD 3 (v 1= 0, 1)→ HF (v)+ CD 3 (v) and DF (v)+ …

Untangling the chemical evolution of Titan's atmosphere and surface–from homogeneous to heterogeneous chemistry

RI Kaiser, P Maksyutenko, C Ennis, F Zhang… - Faraday …, 2010 - pubs.rsc.org
In this article, we first explored the chemical dynamics of simple diatomic radicals (dicarbon,
methylidyne) utilizing the crossed molecular beams method. This versatile experimental …

Accurate ab initio potential energy surface, dynamics, and thermochemistry of the F+ CH4→ HF+ CH3 reaction

G Czakó, BC Shepler, BJ Braams… - The Journal of chemical …, 2009 - pubs.aip.org
An accurate full-dimensional global potential energy surface (PES) for the F+ CH 4→ HF+
CH 3 reaction has been developed based on 19 384 UCCSD (T)/aug-cc-pVTZ quality ab …

Reactive resonance in a polyatomic reaction

W Shiu, JJ Lin, K Liu - Physical review letters, 2004 - APS
In the course of an extensive investigation aimed at understanding the detailed mechanisms
of a prototypical polyatomic reaction, several remarkable observations were uncovered. To …

State-to-state dynamics of elementary bimolecular reactions

X Yang - Annu. Rev. Phys. Chem., 2007 - annualreviews.org
The study of state-to-state dynamics of elementary bimolecular reactions has provided
remarkable insights into chemical reactivity at the most fundamental level. This review …

Imaging chemical reactions–3D velocity mapping

AI Chichinin, KH Gericke, S Kauczok… - International Reviews in …, 2009 - Taylor & Francis
Visualising a collision between an atom or a molecule or a photodissociation (half-collision)
of a molecule on a single particle and single quantum level is like watching the collision of …

The dynamics of chlorine-atom reactions with polyatomic organic molecules

C Murray, AJ Orr-Ewing* - International Reviews in Physical …, 2004 - Taylor & Francis
Chlorine atoms react with a variety of organic molecules by abstraction of an H atom, making
HCl and a radical co-product, and investigations of these reactions provide a large and …

Quantum dynamical resonances in chemical reactions: from A+ BC to polyatomic systems

K Liu - Advances in Chemical Physics, 2012 - Wiley Online Library
2. Differential Cross Section C. The Nature of the Resonance State D. Lessons from This
Benchmark Study V. An Obvious Extension: F+ Methane A. Pair-Correlated ICS of the F+ …