Recent applications of Cp 2 TiCl in natural product synthesis
This review highlights the recent applications of titanocene (III) complexes in the field of
natural product synthesis from the seminal precedents to the development of modern …
natural product synthesis from the seminal precedents to the development of modern …
Bioinspired terpene synthesis: a radical approach
This tutorial review highlights the development of radical-based bioinspired synthesis of
terpenes from the initial proposal to the development of modern catalytic methods for …
terpenes from the initial proposal to the development of modern catalytic methods for …
Enantioselective polyene cyclization via organo-SOMO catalysis
S Rendler, DWC MacMillan - Journal of the American Chemical …, 2010 - ACS Publications
The first organocatalytic enantioselective radical polycyclization has been accomplished
using singly occupied molecular orbital (SOMO) catalysis. The presented strategy relies on a …
using singly occupied molecular orbital (SOMO) catalysis. The presented strategy relies on a …
Enantioselective Reductive Homocoupling of Allylic Acetates Enabled by Dual Photoredox/Palladium Catalysis: Access to C2-Symmetrical 1,5-Dienes
HH Zhang, M Tang, JJ Zhao, C Song… - Journal of the American …, 2021 - ACS Publications
Transition-metal-catalyzed reductive coupling reactions have emerged as powerful
protocols to construct C–C bonds. However, the development of enantioselective C (sp3)–C …
protocols to construct C–C bonds. However, the development of enantioselective C (sp3)–C …
Weakening C− O bonds: Ti (III), a new reagent for alcohol deoxygenation and carbonyl coupling olefination
HR Dieguez, A Lopez, V Domingo… - Journal of the …, 2010 - ACS Publications
Investigations detailed herein, including density functional theory (DFT) calculations,
demonstrate that the formation of either alkoxy− or hydroxy− Ti (III) complexes considerably …
demonstrate that the formation of either alkoxy− or hydroxy− Ti (III) complexes considerably …
An oxidosqualene cyclase makes numerous products by diverse mechanisms: a challenge to prevailing concepts of triterpene biosynthesis
S Lodeiro, Q Xiong, WK Wilson… - Journal of the …, 2007 - ACS Publications
The genome of the model plant Arabidopsis thaliana encodes 13 oxidosqualene cyclases, 9
of which have been characterized by heterologous expression in yeast. Here we describe …
of which have been characterized by heterologous expression in yeast. Here we describe …
Ni-catalyzed reductive homocoupling of unactivated alkyl bromides at room temperature and its synthetic application
Y Peng, L Luo, CS Yan, JJ Zhang… - The Journal of Organic …, 2013 - ACS Publications
A room-temperature Ni-catalyzed reductive approach to homocoupling of unactivated
primary, secondary, and tertiary alkyl bromides is described. The catalytic system can be …
primary, secondary, and tertiary alkyl bromides is described. The catalytic system can be …
Unusually cyclized triterpenoids: occurrence, biosynthesis and chemical synthesis
Covering: 2009 to 2021 Biosynthetically, most of the syntheses of triterpenes follow the
cascade cyclization and rearrangement of the acyclic precursors viz., squalene (S) and 2, 3 …
cascade cyclization and rearrangement of the acyclic precursors viz., squalene (S) and 2, 3 …
A Guide to Low‐Valent Titanocene Complexes as Tunable Single‐Electron Transfer Catalysts for Applications in Organic Chemistry
T Hilche, SL Younas, A Gansäuer, J Streuff - ChemCatChem, 2022 - Wiley Online Library
Low‐valent titanocene catalysts are a versatile tool for organic synthesis. They promote inter‐
and intramolecular reactions ranging from homolytic bond cleavages to reductive umpolung …
and intramolecular reactions ranging from homolytic bond cleavages to reductive umpolung …
The Nugent reagent: a formidable tool in contemporary radical and organometallic chemistry
A Rosales, I Rodríguez‐García… - European Journal of …, 2015 - Wiley Online Library
The vast range of reactions mediated by titanocene monochloride (Cp2TiCl, the Nugent
reagent) in organic synthetic chemistry is reviewed. The power of the Nugent reagent in …
reagent) in organic synthetic chemistry is reviewed. The power of the Nugent reagent in …