Abstract Enantioselective desymmetrization of prochiral 1, 3‐cyclodiketones is the most
convenient and highly desired transformation to access densely functionalized …

Abstract Desymmetrization of prochiral cyclopentene‐1, 3‐diones for the synthesis of
various natural products and moieties of pharmaceutically active compounds, is a very …

In this research, a metal-free diastereoselective formal 1, 3-dipolar cycloaddition of N-2, 2, 2-
trifluoroethylisatin ketimines and cyclopentene-1, 3-diones which can efficiently lead to the …

Utilizing the C4 reactive site of cyclopropyl ketones and a chiral N, N′-dioxide-scandium
(III) complex as a catalyst, a concise ring-opening/cyclization/thio-Michael cascade method …

A chiral N-heterocyclic-carbene-catalyzed cascade asymmetric desymmetrization reaction of
cyclopentenediones with enals has been successfully initiated, followed with tandem aldol …

Catalytic asymmetric synthesis of hydrothiazole derivatives was developed via a well-
organized formal [2+ 1+ 2] cycloaddition reaction triggered by asymmetric addition of …

An efficient approach for the synthesis of chiral pyrrolo [1, 2-d][1, 4] thiazine-2-
carbaldehydes is achieved via formal 1, 3-dipolar cycloaddition/rearrangement reactions of …

[3+ 2] Cycloaddition reactions of heteroaromatic N-ylides with electron-deficient olefins have
been developed. The heteroaromatic N-ylides, in situ generated from N …

Highly efficient asymmetric [3+ 2] cycloaddition reactions of thiazolium salts with a variety of
electron-deficient 2-π components were achieved by chiral N, N′-dioxide/metal complex …

An enantioselective organocatalytic desymmetrization of 2, 2-disubstituted cyclopentene-1,
3-diones via a formal C (sp2)–H amidation is reported. The reaction was carried out with N …