Chromium catalysts for selective ethylene oligomerization to 1-hexene and 1-octene: Recent results
KA Alferov, GP Belov, Y Meng - Applied Catalysis A: General, 2017 - Elsevier
The objective of this review is the analysis and comment of recent publication results (from
July 2010 until February 2017) obtained for selective ethylene oligomerization toward 1 …
July 2010 until February 2017) obtained for selective ethylene oligomerization toward 1 …
Applications of light olefin oligomerization to the production of fuels and chemicals
CP Nicholas - Applied Catalysis A: General, 2017 - Elsevier
The oligomerization of the light olefins ethene, propene, and butenes into fuels and
chemicals has been investigated and commercially practiced for many years. While the area …
chemicals has been investigated and commercially practiced for many years. While the area …
The backbone of success of P, N-hybrid ligands: Some recent developments
MB Smith - Molecules, 2022 - mdpi.com
Organophosphorus ligands are an invaluable family of compounds that continue to underpin
important roles in disciplines such as coordination chemistry and catalysis. Their success …
important roles in disciplines such as coordination chemistry and catalysis. Their success …
Selective ethylene oligomerization
OL Sydora - Organometallics, 2019 - ACS Publications
Ethylene oligomerization to produce 1-alkenes is a cornerstone of organometallic research.
The original α-olefin commercial catalyst system, triethylaluminum, has grown to become …
The original α-olefin commercial catalyst system, triethylaluminum, has grown to become …
A rational approach towards selective ethylene oligomerization via PNP-ligand design with an N-triptycene functionality
Novel PNP ligands bearing an N-triptycene backbone were developed and evaluated for
selective ethylene oligomerization. Upon activation with MMAO-3A, the pre-catalyst mixture …
selective ethylene oligomerization. Upon activation with MMAO-3A, the pre-catalyst mixture …
PNP Ligands in Cobalt‐Mediated Activation and Functionalization of White Phosphorus
AM Kuchkaev, AM Kuchkaev, KR Khayarov… - Angewandte …, 2022 - Wiley Online Library
Transition‐metal mediated white phosphorus activation is of high interest as an ecological
alternative to P4 chlorination pathway to the practically useful phosphorus products. Herein …
alternative to P4 chlorination pathway to the practically useful phosphorus products. Herein …
Phospholane-based ligands for chromium-catalyzed ethylene tri-and tetramerization
SD Boelter, DR Davies, P Margl, KA Milbrandt… - …, 2020 - ACS Publications
Chromium complexes with bis (phospholane) ligands were synthesized and evaluated for
ethylene tetramerization in a high-throughput reactor. Three ligand parameters—the …
ethylene tetramerization in a high-throughput reactor. Three ligand parameters—the …
Evaluation of bis (phosphine) ligands for ethylene oligomerization: discovery of alkyl phosphines as effective ligands for ethylene tri-and tetramerization
SD Boelter, DR Davies, KA Milbrandt, DR Wilson… - …, 2020 - ACS Publications
Fifty-three bis (phosphines) were evaluated as ligands for chromium-catalyzed ethylene
tetramerization in a high-throughput reactor. Selected ligands previously reported in the …
tetramerization in a high-throughput reactor. Selected ligands previously reported in the …
Insights on the mechanism for ethylene tetramerization
BL Small, MF Milner - Organometallics, 2022 - ACS Publications
Selective tetramerization of ethylene to produce 1-octene may be viewed as an extension of
the well-studied process for ethylene trimerization to form 1-hexene, which is commercially …
the well-studied process for ethylene trimerization to form 1-hexene, which is commercially …
Design of Cr-PNP catalysts for ethylene tri-/tetramerization assisted by a data-driven approach
Z Luo, J Peng, Y Mu, L Sun, Z Zhu, Z Liu - Journal of Catalysis, 2023 - Elsevier
The implementation of data-driven methods in the domain of transition metal catalyst design
has emerged as an undeniable trend. With the Curtin-Hammett principle, the selectivity of …
has emerged as an undeniable trend. With the Curtin-Hammett principle, the selectivity of …