Controlled ligand‐based redox‐activity and chemical non‐innocence are rapidly gaining
importance for selective (catalytic) processes. This Concept aims to provide an overview of …

Despite advances in the development of molecular catalysts capable of reducing dinitrogen
to ammonia using proton donors and chemical reductants, few molecular electrocatalysts …

Thermal nitrogen fixation relies on strong reductants to overcome the extraordinarily large
N− N bond energy. Photochemical strategies that drive N2 fixation are scarcely developed …

The complex Ru-MACHO has been previously shown to undergo uncontrolled degradation
subsequent to base-induced dehydrochlorination in the absence of a substrate. In this study …

The splitting of N2 into well‐defined terminal nitride complexes is a key reaction for nitrogen
fixation at ambient conditions. In continuation of our previous work on rhenium pincer …

The complex Ru-MACHO (1) is a widely used precatalyst for hydrogenation and
dehydrogenation reactions under basic conditions. In an attempt to identify the active …

This chapter presents fundamental aspects of the coordination chemistry of N2, including
structure, spectroscopy, reactivity, and catalysis. We start by comparing and contrasting the …

Metal–ligand cooperation is an important aspect in earth-abundant metal catalysis. Utilizing
ligands as electron reservoirs to supplement the redox chemistry of the metal has resulted in …

Complexes {[(PTA) 2CpRu-μ-CN-1 κC: 2 κ 2 N-RuCp (PTA) 2-ZnCl3]}· 2DMSO (13){[ZnCl2
(H2O)]-(PTA-1κ P: 2κ2 N)(PTA) CpRu-μ-CN-1κ C: 2κ2 N-RuCp (PTA)(PTA-1κ P: 2κ2 N) …

Three silyl [PSiP] pincer cobalt (II) chlorides 1–3 [(2-Ph2PC6H4) 2MeSiCo (Cl)(PMe3)](1),[(2-
iPr2PC6H4) 2MeSiCo (Cl)(PMe3)](2) and [(2-Ph2PC6H4) 2MeSiCo (Cl)(LSi:)](LSi:={PhC …