The electronic structure, spectroscopic features, and (catalytic) reactivity of complexes with
nitrogen‐centered radical ligands are described. Complexes with aminyl ([M (. NR2)]) …

Conspectus Transition metal complexes featuring an M═ NR bond have received great
attention as critical intermediates in the synthesis of nitrogen-containing compounds. In …

Herein, we study the mechanism of iron-catalyzed direct synthesis of unprotected
aminoethers from olefins by a hydroxyl amine derived reagent using a wide range of …

We have designed a strategy for postsynthesis installation of the β-diketiminate (NacNac)
functionality in a metal–organic framework (MOF) of UiO-topology. Metalation of the NacNac …

β-Diketiminates are widely used supporting ligands for building a range of metal complexes
with different oxidation states, structures, and reactivities. This Perspective summarizes the …

The 7-coordinate complex [Fe (qpy)(MeCN) 2](ClO4) 2 (1, qpy= 2, 2′: 6′, 2 ″: 6 ″,
2′′′: 6′′′, 2′′′′-quinquepyridine) is a highly active nonheme iron catalyst for …

Reduction of previously reported (ArL) FeCl with potassium graphite furnished a low-spin
(S= 1/2) iron complex (ArL) Fe which features an intramolecular η6-arene interaction and …

Reduction of (ArL) CoIIBr (ArL= 5-mesityl-1, 9-(2, 4, 6-Ph3C6H2) dipyrrin) with potassium
graphite afforded the novel CoI synthon (ArL) CoI. Treatment of (ArL) CoI with a …

Reduction of previously reported iminyl radical (ArL) FeCl (• N (C6H4-pt Bu))(2) with
potassium graphite furnished the corresponding high-spin (S= 5/2) imido (ArL) Fe (N (C6H4 …

Late transition metal oxo complexes with high d-electron counts have been implicated as
intermediates in a wide variety of important catalytic reactions; however, their reactive nature …